原创力文档nitrogen doped carbon nanotubes from organometallic compounds a review氮掺杂碳纳米管的有机金属化合物进行审查.pdfVIP
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nitrogen doped carbon nanotubes from organometallic compounds a review氮掺杂碳纳米管的有机金属化合物进行审查
Materials 2010, 3, 2141-2171; doi:10.3390/ma3032141
OPEN ACCESS
materials
ISSN 1996-1944
/journal/materials
Review
Nitrogen Doped Carbon Nanotubes from Organometallic
Compounds: A Review
Edward N. Nxumalo and Neil J. Coville *
DST/NRF Centre of Excellence in Strong Materials and Molecular Sciences Institute, School of
Chemistry, University of the Witwatersrand, Private Bag 3, Johannesburg 2050, South Africa;
E-Mail: edwardnxumalo@chem.wits.ac.za (E.N.N.)
* Author to whom correspondence should be addressed; E-Mail: neil.coville@wits.ac.za;
Tel.: +27 11 717 6738; Fax: +27 11 717 6749.
Received: 11 February 2010; in revised form: 1 March 2010 / Accepted: 15 March 2010 /
Published: 22 March 2010
Abstract: Nitrogen doped carbon nanotubes (N-CNTs) have become a topic of increased
importance in the study of carbonaceous materials. This arises from the physical and
chemical properties that are created when N is embedded in a CNT. These properties
include modified chemical reactivity and modified conductivity and mechanical properties.
A range of methodologies have been devised to synthesize N-CNTs. One of the procedures
uses a floating catalyst in which an organometallic complex is decomposed in the gas
phase in the presence of a nitrogen containing reactant to give N-CNTs. Most studies have
been limited to ferrocene, ring substituted ferrocene and Fe(CO) . This review covers the
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