polyphosphates as a source of enhanced p fluxes in marine sediments overlain by anoxic waters evidence from 31p nmr聚磷酸盐的增强p通量在海洋沉积物表面由31 p nmr缺氧的水域的证据.pdfVIP

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polyphosphates as a source of enhanced p fluxes in marine sediments overlain by anoxic waters evidence from 31p nmr聚磷酸盐的增强p通量在海洋沉积物表面由31 p nmr缺氧的水域的证据.pdf

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polyphosphates as a source of enhanced p fluxes in marine sediments overlain by anoxic waters evidence from 31p nmr聚磷酸盐的增强p通量在海洋沉积物表面由31 p nmr缺氧的水域的证据

GEOCHEMICAL TRANSACTIONS VOLUME 6, NUMBER 3 SEPTEMBER 2005 Polyphosphates as a source of enhanced P ﬂuxes in marine sediments overlain by anoxic waters: Evidence from 31P NMR Poulomi Sannigrahi and Ellery Ingall School of Earth and Atmospheric Sciences, Georgia Institute of Technology, 311 Ferst Drive, Atlanta, Georgia 30332-0340 Received 10 February 2005; accepted 12 May 2005; published 22 June 2005 Sedimentary phosphorus P composition was investigated in Efﬁngham Inlet, a fjord located on the west coast of Vancouver Island in Barkley Sound. Solid-state 31P nuclear magnetic resonance NMR spectroscopy was applied to demineralized sediment samples from sites overlain by oxic and anoxic bottom waters. The two sites were similar in terms of key diagenetic parameters, including the mass accumulation rate, integrated sulfate reduction rate, and bulk sediment organic carbon content. In contrast, P benthic ﬂuxes were much higher at the anoxic site. 31P NMR results show that P esters and phosphonates are the major organic P species present at the surface and at depth in sediments at both sites. Polyphosphates were only found in the surface sediment of the site overlain by oxic waters. The varying stability of polyphosphates in microorganisms under different redox conditions may, in part, explain their distribution as well as differences in P ﬂux between the two sites. © 2005 American Institute of Physics. DOI: 10.1063/1.1946447 I. INTRODUCTION limited.29 In addition to redox sensitive P cycling mecha- nisms, very little is