preparation of poly(oxybutyleneoxymaleoyl) catalyzed by a proton exchanged montmorillonite clay制备聚(oxybutyleneoxymaleoyl)催化质子交换蒙脱石粘土.pdfVIP

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preparation of poly(oxybutyleneoxymaleoyl) catalyzed by a proton exchanged montmorillonite clay制备聚(oxybutyleneoxymaleoyl)催化质子交换蒙脱石粘土.pdf

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preparation of poly(oxybutyleneoxymaleoyl) catalyzed by a proton exchanged montmorillonite clay制备聚(oxybutyleneoxymaleoyl)催化质子交换蒙脱石粘土

Molecules 2004, 9, 968-977 molecules ISSN 1420-3049 Preparation of Poly(oxybutyleneoxymaleoyl) Catalyzed by a Proton Exchanged Montmorillonite Clay Mohammed Issam Ferrahi * and Mohammed Belbachir Laboratoire de Chimie des Polymères, Département de Chimie, Faculté des Sciences, Université d’Oran Es-Sènia BP N° 1524 El M’Naouar, 31000 Oran, Algeria; Fax: (+213) * To whom correspondence should be addressed; e-mail: mohammed.ferrahi@ Received: 12 July 2004 / Accepted: 6 September 2004 / Published: 30 November 2004 Abstract : The polycondensation of tetrahydrofuran with maleic anhydride catalyzed by Maghnite-H+ (Mag-H) was investigated. Maghnite is a montmorillonite sheet silicate + clay that is exchanged with protons to produce Maghnite-H [1]. It was found that the polymerization in bulk is initiated by Mag-H in the presence of acetic anhydride at 40°C. The effects of the amounts of Mag-H and acetic anhydride were studied. The polymerization yield increased as the proportions of catalyst and acetic anhydride were increased. Keywords: Maghnite, maleic anhydride, montmorillonite, tetrahydrofuran. Introduction The use of acid treated clays as a solid source of protons in a number of industrially significant reactions continues to be of interest because they constitute a widely available and inexpensive solid source of protons. They were widely employed as cracking catalysts until the 1960s [2] and are still used currently in industrial processes such as the a