原创力文档processing of polymer nanocomposites reinforced with polysaccharide nanocrystals处理与多糖纳米结晶聚合物纳米复合材料的增强.pdfVIP
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processing of polymer nanocomposites reinforced with polysaccharide nanocrystals处理与多糖纳米结晶聚合物纳米复合材料的增强
Molecules 2010, 15, 4111-4128; doi:10.3390/molecules
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Review
Processing of Polymer Nanocomposites Reinforced with
Polysaccharide Nanocrystals
Alain Dufresne †
The International School of Paper, Print Media and Biomaterials (Pagora), Grenoble Institute of
Technology, BP 65 - 38402 Saint Martin dHères Cedex, France;
E-Mail: Alain.Dufresne@pagora.grenoble-inp.fr; Tel.: +33-4-76-82-69-95; Fax: +33-4-76-82-69-33
† Present address: Departamento de Engenharia Metalurgica e de Materiais, Universidade Federal do
Rio de Janeiro (UFRJ), Coppe, Rio de Janeiro, Brazil.
Received: 12 May 2010; in revised form: 2 June 2010 / Accepted: 7 June 2010 /
Published: 8 June 2010
Abstract: Aqueous suspensions of polysaccharide (cellulose, chitin or starch) nanocrystals
can be prepared by acid hydrolysis of biomass. The main problem with their practical use
is related to the homogeneous dispersion of these nanoparticles within a polymeric matrix.
Water is the preferred processing medium. A new and interesting way for the processing of
polysaccharide nanocrystals-based nanocomposites is their transformation into a
co-continuous material through long chain surface chemical modification. It involves the
surface chemical modification of the nanoparticles based on the use of grafting agents
bearing a reactive end group and a long compatibilizing tail.
Keywords: cellulose; nanocomposites; processing; nanocrystals; whiskers; microfibrils
1. Intr
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