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pvc membrane sensors for potentiometric determination of acebutololpvc膜电位测定醋丁洛尔传感器.pdf

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pvc membrane sensors for potentiometric determination of acebutololpvc膜电位测定醋丁洛尔传感器

Sensors 2007, 7, 3272-3286 sensors ISSN 1424-8220 © 2007 by MDPI /sensors Full Research Paper PVC Membrane Sensors for Potentiometric Determination of Acebutolol Gamal Abdel-Hafiz Mostafa *, Mohamed Mahmoud Hefnawy and Abdulrahman Al-Majed Pharmaceutical Chemistry Department, College of Pharmacy, King Saud University, P.O.Box 2457, Riyadh11451, Saudi Arabia. *Corresponding Author. E-mail: gamal_most@ Received: 11 July 2007 / Accepted: 8 October 2007 / Published: 13 December 2007 Abstract : The construction and general performance characteristics of two novel potentiometric membrane sensors responsive to the acebutolol are described. The sensors are based on the use of ion-association complexes of acebutolol (AC) with tetraphenylborate(TPB) (I) and phosphomolybdate(PM) (II) as exchange sites in a PVC matrix. The sensors show a fast, stable and near- Nernstian for the mono charge cation -3 - ~10-6 M at 25 °C over the pH range 2.0 - of AC over the concentration range 1×10 6.0 with cationic slope of 51.5 ± 0.5 and 53.0 ± 0.5 per concentration decade for AC-I -6 -6 and AC-II sensors respectively. The lower detection limit is 6×10 M and 4×0 M with the response time 20-30 s in the same order of both sensors. Selectivity coefficients of AC related to a number