quartz crystal nanobalance in conjunction with principal component analysis for identification of volatile organic compounds石英晶体nanobalance结合主成分分析对挥发性有机化合物的识别.pdfVIP

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quartz crystal nanobalance in conjunction with principal component analysis for identification of volatile organic compounds石英晶体nanobalance结合主成分分析对挥发性有机化合物的识别.pdf

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quartz crystal nanobalance in conjunction with principal component analysis for identification of volatile organic compounds石英晶体nanobalance结合主成分分析对挥发性有机化合物的识别

Sensors 2006, 6, 324-334 sensors ISSN 1424-8220 © 2006 by MDPI /sensors Quartz Crystal Nanobalance in Conjunction with Principal Component Analysis for Identification of Volatile Organic Compounds Abdolreza Mirmohseni 1,*and Kobra Rostamizadeh 1,2 1Polymer Research Technology Laboratory, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Iran 2Research Center for Pharmaceutical Nanotechnology, Tabriz University of Medical Science, Tabriz, Iran * Author to whom correspondence should be addressed. Email: mirmo@.au Received: 6 July 2005 / Accepted: 4 January 2006 / Published: 7 April 2006 Abstract: Quartz crystal nanobalance (QCN) sensors are considered as powerful mass- sensitive sensors to determine materials in the sub-nanogram level. In this study, a single piezoelectric quartz crystal nanobalance modified with polystyrene was employed to detect benzene, toluene, ethylbenzene and xylene (BTEX compounds). The frequency shift of the QCN sensor was found to be linear against the BTEX compound concentrations in the range about 1-45 mg l-1. The correlation coefficients for benzene, toluene, ethylbenzene, and xylene were 0.991, 0.9977, 0.9946 and 0.9971, respectively. The principal component analysis was also utilized to process the frequency response data of the single piezoelectric crystal at different times, considering to the different adsorption-desorption dynamics of BTEX compounds. Using principal component analysis, i