reactivity of ruthenium vinylidene complexes containing indenyldppe ligands and unsaturated bonds at cd with trimethylsilyl azide反应性含indenyldppe亚乙烯基钌配合物配体和不饱和键与叠氮化三甲基硅烷基的cd.pdfVIP

下载本文档

2
0
约9.61万字
约 21页
2017-09-11 发布于上海
举报
版权申诉

reactivity of ruthenium vinylidene complexes containing indenyldppe ligands and unsaturated bonds at cd with trimethylsilyl azide反应性含indenyldppe亚乙烯基钌配合物配体和不饱和键与叠氮化三甲基硅烷基的cd.pdf

1、本文档共21页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

reactivity of ruthenium vinylidene complexes containing indenyldppe ligands and unsaturated bonds at cd with trimethylsilyl azide反应性含indenyldppe亚乙烯基钌配合物配体和不饱和键与叠氮化三甲基硅烷基的cd

Molecules 2012, 17, 8533-8553; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Reactivity of Ruthenium Vinylidene Complexes Containing Indenyl/dppe Ligands and Unsaturated Bonds at C with Trimethylsilyl Azide Hui-Ling Sung 1,*, Tze-Min Her 2, Wen-Hsien Su 2 and Chin-Pao Cheng 3 1 Department of Mathematics and Science (Pre-college), National Taiwan Normal University, New Taipei City 244, Taiwan 2 Department of Chemical and Materials Engineering, Lunghwa University of Science and Technology, Taoyuan County 333, Taiwan; E-Mails: ch007@.tw (T.-M.H.); cower1987.tw@ (W.-H.S.) 3 Department of Mechatronic Technology, National Taiwan Normal University, Taipei 106, Taiwan; E-Mail: cpcheng@.tw * Author to whom correspondence should be addressed; E-Mail: hlsung@.tw; Tel.: +886-2-7714-8390; Fax: +886-2-2602-2617. Received: 13 June 2012; in revised form: 5 July 2012 / Accepted: 6 July 2012 / Published: 17 July 2012 Abstract: This study presents a new reaction of cationic vinylidene complexes with Me SiN (TMSN ), which yields N-coordinated nitrile complexes 3. Treatment of a 3 3 3 ruthenium acetylide precursor containing indenyl and dppe ligands with a series of organic halides produced the corresponding vinylidene complexes 2 in good yield. Further reaction of 2 with TMSN3 at room temperature produced N-coordinated ruthenium nitrile complexes 3. Unlike the reaction of cyclopropenylrutheni