ruthenium carbene mediated metathesis of oleate-type fatty compounds钌碳烯介导oleate-type脂肪化合物的置换作用.pdfVIP

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ruthenium carbene mediated metathesis of oleate-type fatty compounds钌碳烯介导oleate-type脂肪化合物的置换作用.pdf

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ruthenium carbene mediated metathesis of oleate-type fatty compounds钌碳烯介导oleate-type脂肪化合物的置换作用

Int. J. Mol. Sci. 2008, 9, 615-625 International Journal of Molecular Sciences ISSN 1422-0067 © 2008 by MDPI /ijms/ Full Research Paper Ruthenium Carbene Mediated Metathesis of Oleate-Type Fatty Compounds Bassie B. Marvey 1,*, Constance K. Segakweng 1 and Manie H. C. Vosloo 2 1 Department of Chemistry, North-West University, P/Bag X2046, Mafikeng, 2735, South Africa 2 School of Chemistry, North-West University, P/Bag X6001, Potchefstroom, South Africa *Author to whom correspondence should be addressed; Tel. +27-18-389 2527; Fax: +27 18 389 2052; E-mails: bassie.marvey@nwu.ac.za; cksegakweng@webmail.co.za; manie.vosloo@nwu.ac.za Received: 16 November 2007; in revised form: 28 March 2008 / Accepted: 17 April 2008 / Published: 18 April 2008 Abstract: The complexes RuCl (PCy ) (=CHPh), 1, and RuCl (PCy )(H IMes)(=CHPh), 2 3 2 2 3 2 2, proved to be active catalysts for the self-metathesis of oleate-type fatty compounds containing the ester, hydroxyl, epoxy and carboxylic acid functional groups. At elevated reaction temperatures 2 showed a higher activity, stability and lower selectivity for primary metathesis products compared to 1. A profound influence of organic functional groups on catalyst activity and selectivity was found and from relative activities and selectivities 2 has proved to be more resistant to deactivation by