selective formation of twisted intramolecular charge transfer and excimer emissions on 2,7-bis(4-diethylaminophenyl)-fluorenone by choice of solvent选择性的形成扭曲的分子内电荷转移和准分子排放2日,7-bis(4-diethylaminophenyl)芴酮溶剂的选择.pdfVIP

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selective formation of twisted intramolecular charge transfer and excimer emissions on 2,7-bis(4-diethylaminophenyl)-fluorenone by choice of solvent选择性的形成扭曲的分子内电荷转移和准分子排放2日,7-bis(4-diethylaminophenyl)芴酮溶剂的选择.pdf

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selective formation of twisted intramolecular charge transfer and excimer emissions on 2,7-bis(4-diethylaminophenyl)-fluorenone by choice of solvent选择性的形成扭曲的分子内电荷转移和准分子排放2日,7-bis(4-diethylaminophenyl)芴酮溶剂的选择

Molecules 2012, 17, 4452-4459; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Communication Selective Formation of Twisted Intramolecular Charge Transfer and Excimer Emissions on 2,7-bis(4-Diethylaminophenyl)- fluorenone by Choice of Solvent Masayuki Shigeta 1, Mifumi Morita 1 and Gen-ichi Konishi 1,2,* 1 Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, Tokyo 152-8552, Japan 2 PRESTO, Japan Science and Technology Agency, Saitama 332-0012, Japan * Author to whom correspondence should be addressed; E-Mail: konishi.g.aa@m.titech.ac.jp; Tel.: +81-3-5734-2321; Fax: +81-3-5734-2888. Received: 1 March 2012; in revised form: 30 March 2012 / Accepted: 6 April 2012 / Published: 13 April 2012 Abstract: We designed and synthesized a donor-acceptor-donor dye consisting of a 2,7-disubstituted fluorenone with diethylaminophenyl moieties present as strong electron donating groups. Switching between twisted intramolecular charge transfer (TICT) emission and excimer emission was achieved, with no ground state changes, by simply changing the solvent used. In a nonpolar solvent, excimer emission was observed; with increasing polarity, the emission gradually disappeared, and the TICT emission appeared. Keywords: twisted intramolecular charge transfer (TICT); excimer; intermolecular charge transfer; fluorenone; donor acceptor dye 1. Introduction Twiste