生物化学讲义-----川大张洪渊（Biological chemistry, Sichuan Zhang Hongyuan）.docVIP

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生物化学讲义-----川大张洪渊（Biological chemistry, Sichuan Zhang Hongyuan）.doc

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生物化学讲义-----川大张洪渊（Biological chemistry, Sichuan Zhang Hongyuan）

生物化学讲义-----川大张洪渊（Biological chemistry, Sichuan Zhang Hongyuan） Second chapter saccharide The concept of section 1. of sugar I. kinds and functions of sugar 1. definition of sugar 2. the function of sugar: energy structure information transfer 3. kinds of sugar: Monosaccharide: defined as an example of the union of ketones, ketones, sugars, propyl, butyl, amyl, self, and sugar, and their combinations Oligosaccharides: definitions, examples Polysaccharides: examples of polysaccharides defined as polysaccharides Bound sugars: definitions, examples 4. carbs: carbohydrate Two. Configuration of sugar 1. several concepts: Isomer Structural isomerism Stereochemical isomerism Geometric isomerism Optical isomerism Differential isomerism 2. configuration of sugar Properties of optically polarized isomers of asymmetric carbon atoms The conformation (D\L) significance of glyceryl aldehyde Glucose configuration The structure and properties of 2. monosaccharides Monosaccharide example I. structure of glucose 1. chain structure: conditional structure, configuration, optical isomer and natural selection, simplified structure 2., ring structure: conditional type and furan type, and natural selection of alpha and beta types 3. projection (Haworth) chain and ring type interconversion rules 4., the phenomenon of spin: the essence of phenomena 5. conformation of glucose: boat type and chair type 6. the structural formula of several important monosaccharides (default type D-): glyceryl aldehyde, dihydroxy acetone, ribose! Deoxy ribose! Glucose, mannose, galactose, candy! Both chain and ring, please find them in your book. Two. Properties of monosaccharides 1. physical properties: Opticity (special) Sweetness: standard and order (fructose sucrose glucose) Solubility 2. chemical properties 1. and the action of strong acids: the formation of furfural and its derivatives Formula and principle: Book P16 Identification of sugar: Molish reaction: Compound furfural and its derivatives with alph