褐煤等温脱水热重分析.pdfVIP

第29 卷 第14 期 中 国 电 机 工 程 学 报 Vol.29 No.14 May 15, 2009 74 2009 年5 月15 日 Proceedings of the CSEE ©2009 Chin.Soc.for Elec.Eng. 0258-8013 (2009) 14-0074-06 TQ 028 A 470 10 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 褐煤等温脱水热重分析 赵卫东，刘建忠，周俊虎，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) Investigation on the Isothermal Dewatering of Brown Coal by Thermobalance ZHAO Wei-dong, LIU Jian-zhong, ZHOU Jun-hu, CEN Ke-fa (State Key Laboratory of Clean Energy Utilization (Zhejiang University), Hangzhou 310027, Zhejiang Province, China) ABSTRACT: Using thermobalance, four kinds of brown coal 缩，按照 Kelvin 公式，该过程主要受毛细管作用力影响， were dried under the flow of nitrogen and isothermal 蒸发速率逐渐降低；含水率低于临介含水率阶段对应褐煤内 conditions. With thermogravimetric (TG) and differential 部微孔内水分的干燥，由于褐煤表面富含含氧官能团，并与 thermogravimetric (DTG) methods, the curves of evaporation 水通过氢键连接，水的蒸发速率变得更低，蒸发过程主要受 rates versus moisture contents were plotted and the mechanism 脱附/吸附以及氢键破坏作用控制。 equations of different drying stages were obtained. Samples 关键词：褐煤；热天平；脱水；干燥机理 before and after drying were also analysed by scanning electron microscope (SEM). Results show that under the condition of 0 引言 nitrogen flow in thermobalance, coal bulk decreases as the 褐煤挥发分含量高(V 40%) ，干煤易着火、 daf micro-morphology changes; the drying process can be divided 易燃尽；但褐煤存在湿度大(收到基含水量 30%~ into two