氨基修饰磁性氧化石墨烯吸附离子型染料性能.pdfVIP

中国环境科学 2016,36(7) ：2020~2026 China Environmental Science 氨基修饰磁性氧化石墨烯吸附离子型染料性能 * 魏金枝,陈芳妮,孙晓君 ,张凤鸣,王 虹 (哈尔滨理工大学化学与环境工程学院,黑龙江 哈尔滨 150040) 摘要：采用恒温搅拌法和水热法首次制备磁性三乙烯四胺氧化石墨烯(M-T-GO),并通过 SEM 和 XPS 对 M-T-GO 进行表征.以 M-T-GO 为吸附剂,分析 pH 值、吸附时间和初始浓度对阴离子染料酒石黄(TY)和阳离子染料亚甲基蓝(MB)吸附效果的影响.并对吸附动力学和吸附 等温线进行拟合.结果表明:M-T-GO 对离子型染料的吸附过程符合 Langmuir 吸附等温式和拟二级反应动力学描述.M-T-GO 对 TY 和 MB 具有较好的吸附性能,饱和吸附量分别为 157.23mg/g 和 169.49mg/g.与 GO 相比,M-T-GO 对离子型染料的吸附效果更优异, 同时具有快速 分离和易再生的优点. 关键词：氧化石墨烯；三乙烯四胺；磁性；吸附；离子型染料 中图分类号：X592 文献标识码：A 文章编号：1000-6923(2016)07-2020-07 Adsorption performance of amino functionalized magnetic graphene oxide composite to ionic dyes. WEI Jin-zhi, * CHEN Fang-ni, SUN Xiao-jun , ZHANG Feng-ming, WANG Hong (College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Haerbin 150040, China). China Environmental Science, 2016,36(7) ：2020~2026 Abstract ：Magnetic Triethylene-tetramine Graphene oxide (M-T-GO) was firstly synthesized by constant temperature stirring and hydrothermal methods in this work, and characterized by Scanning electron microscope (SEM) and X-ray photoelectron spectrum (XPS). Adsorption capacity of ionic dyes on M-T-GO under different pH, adsorption time and initial concentration were investigated. At the same time adsorption kinetics and adsorption isotherm were fitted respectively. Pseudo-second-order model and Langmuir model fitted the adsorption of ionic dyes on M-T-GO. The adsorption property of M-T-GO for TY and MB was outstanding and the saturated adsorption capacities were 157.23mg/g and 169.49mg/g, respectively. Compared with GO, M-T-GO could remove ionic dyes more effectively. Moreover,