聚乳酸增韧研究进展综述与专论.pdfVIP

化 工 进 展 2015 年第34 卷第11 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·3975 · 综述与专论 聚乳酸增韧研究进展 邓艳丽，杨斌，苗继斌，苏丽芬，夏茹，陈鹏，钱家盛 （安徽大学化学化工学院，绿色高分子材料安徽省重点实验室，安徽合肥 230601 ） 摘要：总结了聚乳酸增韧改性方面的最新研究进展，为新型聚乳酸复合材料的研究开发提供理论依据；概述了 共混、复合、共聚、交联、增塑以及添加成核剂等几种增韧技术，并比较了不同增韧方法的特点；通过对合成 方法的改进以及进行共混、共聚、复合及增塑等改性，可以显著改善聚乳酸材料的力学性能并同时保持耐热性 和降解性能不受影响；开发更加高效的增韧改性剂，增加其与聚乳酸分子链间的界面相互作用并提高复合材料 的冲击性能已成为研究工作的努力方向。从微观分子尺度上对聚乳酸进行增韧改性以及设计绿色合成路线仍是 目前研究工作的重点。 关键词：聚乳酸；降解；增韧；聚合物加工；成核 中图分类号：TQ 316.2 文献标志码：A 文章编号：1000 –6613 （2015 ）11 –3975 –04 DOI ：10.16085/j.issn.1000-6613.2015.11.023 Research progress in the toughening modification of polylactic acid DENG Yanli ，YANG Bin，MIAO Jibin ，SU Lifen ，XIA Ru ，CHEN Peng，QIAN Jiasheng （College of Chemistry and Chemical Engineering，Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province ，Anhui University ，Hefei 230601 ，Anhui ，China ） Abstract ：The latest research progress in toughening modification of poly lactic acid (PLA) was summarized in this work，so as to provide a theoretical basis for the research and development of novel PLA-based composite materials. Physical modification ，chemical modification，plasticization ，as well as several other toughening technologies were outlined ，and comparison among them was also presented. The material physical and mechanical properties ，optical performance and heat resistance of PLA can be significantly improved through the use of new synthetic method and blending ， copolymerization，etc. The development of more efficient toughening modifier，in an attempt to enhance the interfacial interactions between PLA and the toughening fillers，is the direction of further study on PLA. The inves