连铸结晶器铜板电镀 Cu-Ni 技术的应用研究.pdfVIP

连铸结晶器铜板电镀Cu-Ni 技术的应用研究 ·1 · 连铸结晶器铜板电镀Cu-Ni 技术的应用研究 白新波1 （宝钢工程集团 宝钢工业技术服务有限公司，上海 201900 ） 摘 要 连铸拉坯时，结晶器铜板表面镀层不断磨损，磨损到一定程度后，需下线对铜板进行电镀修复。为保证镀 层与结晶器铜板有良好的结合力，电镀之前，要把铜板上镀层铣除干净，去除残余镀层过程中不可避免会铣掉部分 基材，经过若干次处理后铜板逐渐变薄直至报废。本文探讨了一种恢复结晶器铜板厚度的电镀方法，延长其寿命和 报废期限。通过循环伏安曲线，对焦磷酸盐体系中 Cu-Ni 合金的共沉积过程进行了探讨，结果表明，在焦磷酸体系 中可以实现Cu-Ni 共沉积。采用恒电流电沉积的方法制备出了 Cu-Ni 合金镀层，结果表明镀层的形貌、结合力和导 电性良好，Cu-Ni 合金镀层与基体铬锆铜相比，硬度和耐腐蚀性都有显著提高，这为该镀层在铜板上的应用、延长 铜板使用寿命提供了可能。 关键词 连铸结晶器，Cu-Ni 镀层，共沉积，焦磷酸盐，性能 Application Research of Cu - Ni Electrodeposition Technology on Continuous Casting Mould Bai Xinbo (Baosteel Industry Technological Services Co., Ltd., Baosteel Engineering Group Co., Ltd., Shanghai 201900, China) Abstract In the course of work, the surface coatings of continuous casting mold would wear and get thinner. It is need to repair the mold by plating when the coating wears to a certain extent. Prior to electroplating, the residual coating should be cleaned with a mill, portion of the substrate will be milled out inevitably in the process. After several times, the mold gets thinner and thinner gradually until retirement. An electroplating method to recover the thickness of continuous casting mould was discussed. The process of co-deposition of Cu-Ni alloy was discussed by cyclic voltammetry. The results show that copper and nickle can be co-deposited in pyrophosphate. And Cu-Ni alloy coating were prepared by constant current deposition. Morphology, electrical conductivity and adhesion and of the coating are good. Compared with copper plate (Cu-Cr-