Reduction of Cr during Smelting Treatment of Stainless Steel Dust论文.pdfVIP

Reduction of Cr during Smelting Treatment of Stainless Steel Dust ·1 · Reduction of Cr during Smelting Treatment of Stainless Steel Dust Zhang Yanling, Jia Xinlei, Guo Wenming (State Key Laboratory of Advanced Metallurgy, University of Science and Technology, Beijing 100083, China) Abstract Staniless steel dust contains a remarkable content of Cr oxides which is worthrecycling.As a practical method, Smelting treatment is chosen to recover Cr resource in stainless steel dust. Distribution of Cr between the recovered melt and the residual slag phase depends on the activity coefficient of Cr in the metal phase (γ ) and the activity coefficient of Cr CrO in the slag (γ ). Bothγ inFe-Cr-Ni-C (-Si/Al) melt and γ in CaO-SiO -MgO-Al O slag under different CrO Cr CrO 2 2 3 situations were firstlypredicted through thermodynamic calculation. Experimental research on reduction of Cr during smelting treatment of stainless steel dust was performed in this study. Theresults suggested that the recovery ratios of valuable metals increased with increasing %CaO/%SiO2 of the residual slag to 1.17 and then decreased.A good linear relationship betweenthe apparent distribution ratio of Cr ( Lm/s ) and γ /γ was observed. Cr CrO Cr K