溶剂萃取法从镀锌酸洗废液中分离锌铁的研究.PDFVIP

23 5 矿　冶　工　程 Vol.23 №5 2003 10 MINING AND METALLURGICAL ENGINEERING October 2003 、 1 1 2 2 2 3 汤　兵, 朱又春, 白雪梅, 蔡　斌, 陈丽卿, 张俊浩 (1., 510090;2.,510450;3., 510090) 　:、。 :H SO-N -, O/A=1∶1, N 2 4 263 263 - - 20%, Cl 、, Cl 1 ∶4 , 501.3, , 、。 :;;;; Study of Separating of Zinc from Iron in Waste Sulfuric Acid Pickle Liquor by Solvent Extraction 1 1 2 2 2 3 TANG Bing , ZHU You-chun , BAI Xue- ei , CAI Bin , CHEN Li-qing , ZHANG Jun-hao (1.Faculty of Environmental Scinece and Engineering, Guangdong University of Technology, Guangzhou 510090, Guang- dong, China;2.Guangdong ElectricLineAppliancefactory, Guangzhou 510450, Guangdong, China;3.CentralLaborato- ry, Guangdong University of Technology, Guangzhou 510090, Guangdong, China) Abstract:A study is adeof separation of zincfro iron inwaste sulfuric acid pickle liquor by solvent extraction.The results - showed that in the H2SO4-N263-kerosenesyste , addition of Cl to aqueous phase can arkedly i prove the separation of zinc - fro iron at a volu e concentration of 20%N263 andO/A ratio 1∶1.When the ol ratio of Cl to etal ion in aqueous phase is 1∶4, the axi u separation coefficient between zincand iron is up to 501.3.A thorough separation of zinc fro iron can be achieved by two-stage counter-current extraction. Key ords:solvent extraction;waste sulfuric acid pickle liquor;separation;zinc;iron 　　 , , , 。, 。 , , , 、 , 。 , 。 , , 、