中温太阳能驱动甲烷化学链重整冷热电系统及性能研究.pdfVIP

中温太阳能驱动甲烷化学链重整冷热电系 统及性能研究 摘 要 针对高温太阳能与天然气热化学互补分布式能源系统存在聚光比高、互补反应温度高、变工况性能不 稳定的技术瓶颈，本文探索了一种能实现主动调控的中温太阳能与天然气互补的化学链重整冷热电联 o 产系统。利用约500 C太阳热能驱动天然气基- 氧化镍化学链重整，生成合成气太阳能燃料，通 燃气轮机冷热电联产系统，实现中温太阳能与天然气 综合梯级利用。研究结果表明：在设计点工况条件下，系统的总能效率可达到80.9%，太阳能集热面积节 约率达到53.2%，太阳能净发电效率可达27.3%。分析了关键参数如NiO和甲烷摩尔比（Ni/C ）和太阳辐 照强度（DNI）对系统热力学性能的影响。 关键词 甲烷；化学链重整冷热电系统；中温太阳能 Analysis of combined cooling, heating and power generation system based on methane chemical looping reforming driven by mid-temp solar energy 1,2 1 1,2 1 FAN Jun-ming , HONG Hui , ZHANG Hao , JIN Hong-guang (1. Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, PR China 2. University of Chinese Academy of Sciences, Beijing 100049, PR China) Abstract In order to deal with the bottlenecks associated with the energy utilization within high-temp solar hybrid methane combined cooling, heating and power system, i.e. high concentration ratio, high reaction temperature and unstable condition, a novel concept by combined cooling, heating and power generation system based on methane chemical looping reforming driven by mid-temp solar energy is explored and analysed. In this system, the energy required for driving chemical looping reforming of methane with NiO is originated from mid-temp solar energy at approximately 500 oC. And the chemical energy of methane and solar energy are together converted into chemical energy contained in syngas. The energy contained in syngas is further utilized for combined cooling, heating and power generation, fulfilling the aim of cascade energy utilization of methane and solar energy. According to the results, it shows the total energy efficiency of this novel system can be reached at 80.9%，and the solar area saving ratio can be maximized to be 53