铵浸法由白云石制备高纯度碳酸钙和氧化镁-中国科技论文在线.PDFVIP

中国科技论文在线 第37 卷第2 期 无机盐工业 2005 年2 月 INORGANIC CHEMICALS INDUSTRY 27 , , ( , 710062) : , , , , , : ; ; ; :TQ132. 32 :A :1006- 4990(2005)02- 0027- 03 The preparation of high purity calcium carbonate and magnesia by ammonium salt extracting method from dolomite Bai Yunshan, Liu Taihong, Liu Zhen ( College of Chemistr y and M ater ials Science, Shanx i N or mal Univ ersity , Shanx i Xian 710062, China) Abstract: Th edolomit eis calcined to form th emixtur eof calcium oxid eand magnesia,then th emixtur eis extracted by ammonium chlorid esolution and ammonium sulfat esolution respectively.Th xtractiv ecalcium chlorid esolution reacts with CO in th epresenc eof different crystal- shap econtroller, th ehigh- purity spheric and cubic calcium carbonat ewith 2 different particl esiz eis obtained.T h xtractiv emagnesium sulfat ereacts with ammonium carbonate,th ehigh- purity and activity magnesia is obtained.A series of influenc efactors, such as reaction temperature,concentration of solution and th species of crystal controller in th eprocess ar estudied. And th eoptimum reaction conditions ar edetermined. By this method, calcium and magnesium in dolomit ear ewell separated. Key words: dolomite;calcium carbonate;magnesia;crystal- shap econtroller : Quanta 200 950~ 1 000 1. 3 , , , GB4794 1984 ; , GB9004 1988 , , 1. 4 [1,2] 1) : 5 cm 3 cm 2 cm , SRJX- 4- 13 ,