2010-3 加氢处理.ppt

石油炼制工程;Hydrodesulfurisation (HDS)加氢脱硫;Market share of main catalysts technology divisionsin percentage in terms of sales value催化剂市场份额; Hydrodenitrogenation (HDN)加氢脱氮 Hydrodesulfurization （HDS)加氢脱硫 Hydrodeoxygenation (HDO)加氢脱氧 Hydrodemetallization (HDM)加氢脱金属 ;Hydrotreating加氢处理: A process used in the oil industry to remove objectionable elements such as nitrogen sulfur, oxygen and metals from petroleum distillates by reacting them with H2 over a catalyst. 加氢处理工艺是利用氢气与油品发生催化加氢反应脱除油品中有害的杂质成份，如氮、硫、氧和重金属等。;;;Compound 馏分;HDS加氢脱硫 Prevention of poisoning of the metal catalysts by sulfur防止金属催化剂中毒 Control of pollution by SO2 produced in the combustion of gasoline减控汽车排放硫污染 Removal of the unpleasant odour of lube oil caused by the presence of sulfur脱除油品的臭气味。 ;HDN加氢脱氮 Nitrogen High nitrogen concentrations containing compounds severely reduce the activity of cracking, hydrogenation, isomerisation, reforming and HDS catalysts are detrimental to product quality To meet the NOx emission restrictions. If present, N-compounds affect the stability of fuels.;COMPOUND;Typical Sulfur Compounds and their Hydrotreating pathway典型的硫化物和它们的加氢处理途径;Reactivity of various organic sulfur compounds in HDS加氢脱硫中的各种有机活性硫化合物;1、常规的加氢脱硫 When organo sulfur compounds are decomposed, gaseous or solid sulfur products are formed and the hydrocarbon part is recovered and remains in the refinery streams. Conventional HDS（加氢脱硫 2、物理脱硫 Sulfur compounds are separated from refinery stream without decomposition 3、有机硫的化学反应与分离 Organo sulfur compounds are separated from the streams and simultaneously decomposed in a single reactor unit rather than in a series of reaction and separation vessels;Desulfurization technologies classified by nature of a key process to remove sulfur脱硫技术按脱硫方式分类;Co is present in threedifferent phases.钴存在于三相中 (i) The active CoMoS nanoparticles. (ii) A thermodynamically stable  cobalt sulfide, Co9S8热力学稳定的硫化钴. (iii) Co dissolved in the Al2O3 support.Only t