树枝化聚合物的合成结构表征及其应用.pdfVIP

第 17 卷 第 1 期 化　学　进　展 Vol. 17 No. 1 2005 年 1 月 PROGRESS IN CHEMISTRY 　Jan. , 2005 树枝化聚合物的合成、结构表征及其应用3 张阿方3 3 (郑州大学材料工程学院 　郑州 450052) 摘 　要 　本文综述了由树枝状大分子和线形聚合物结合而形成的一类新型树形聚合物 ———树枝化聚合 物的研究进展 ,包括树枝化聚合物的各种合成方法、结构表征和形态分析等。同时对树枝化聚合物在催化载 体、纳米材料、生化和光电功能材料等领域的应用研究进行了详尽的综述。 关键词 　树枝化聚合物 　树枝状大分子 　树形聚合物 　聚合反应 　纳米聚合物 ( ) 中图分类号: O63111 　文献标识码 : A 　文章编号 : 2005 0120157215 Synthesis , Characterization and Applications of Dendronized Polymers 3 3 Zhang Afang (College of Materials Engineering , Zhengzhou University , Zhengzhou 450052 , China) Abstract 　This review highlights the recent development of synthesis , characterization and applications of den2 dronized polymers. Two different synthetic routes , e. g. macromonomer route and divergent route , are compared based on the achievable molar mass and structure perfection of the resulted dendronized polymers. A comprehensive overview on the kind of structures presently available for dendronized polymer and the bridge between both polymers and molecular ob2 jects , decorated with only a few dendrons , and the structurally related , but less well defined polymers with hyper2 branched side chains or cross2linked backbone is given. Structure characterization by NMR , GPC and light scattering , together with morphology and bulky properties analysis are detailed. Emphases are applied to nano catalysis , nano bio2 objects , and optic applications. Key words 　dendronized polymer