石墨烯聚乳酸复合材料的制备与性能研究.PDFVIP

第37卷第9期 包装工程 2016年5月 PACKAGINGENGINEERING 7 石墨烯/聚乳酸复合材料的制备与性能研究 谢元仲，徐淑艳，张维丽，孟令馨 （东北林业大学，哈尔滨150040） 摘要：目目的的 制备具有优异阻隔性能及热稳定性的聚乳酸薄膜材料。方方法法 在聚乳酸中添加石墨烯对 其进行改性。首先采用改进的Hummers法将鳞片状石墨制备成氧化石墨烯，继而采用热剥离法将氧 化石墨烯还原剥离为石墨烯，然后以聚乳酸为基材，还原后的石墨烯为增强相，采用流延法制备石墨 烯/聚乳酸复合薄膜，并测试了其结构、热稳定性以及阻隔性能。结结果果 红外分析表明，石墨被强氧化 剂氧化后形成了以C—OH，—COOH，C—O—C和C＝O等官能团形式存在的石墨层间化合物，还原 后获得的石墨烯剥离充分；石墨烯/聚乳酸复合薄膜的热稳定性能和阻隔性能随石墨烯含量的增加而 逐渐增强。结结论在试验参数范围内，石墨烯论 /聚乳酸复合薄膜的热稳定性和阻隔性能优于聚乳酸薄膜。 关键词：石墨烯；聚乳酸；阻隔性能；热稳定性 中图分类号：TB484.9 文献标识码：A 文章编号：1001-3563（2016）09-0007-05 PreparationandPropertiesofGrapheneandPolylacticAcidComposites XIE Yuan-zhong ，XU Shu-yan ，ZHANG Wei-li ，MENG Ling-xin （NortheastForestryUniversity，Harbin150040，China） ABSTRACT：This work was aimed to obtain polylactic acid films with good barrier properties and thermal stability. Graphene was added into polylactic acid to modify it. Graphene oxide was prepared using the flaky graphite by the improved Hummers method. Graphene oxide was reduced to graphene by thermal stripping method. Grapheme/ polylactic acid films were prepared with tape casting method, using polylactic acid as the substrate and graphene as the reinforcement. The structure, thermal stability and barrier properties of films were tested. Infra-red spectrogram showed that graphite intercalation compound with COOH, C ＝O, C—O—C and C—OH functional groups was formed when graphite was oxidized by the strong oxidizer, and graphene stripped sufficiently by reduction. The thermal stability performance and barrier properties of graphene and lactic acid composite films increased with the increasing graphene content. Within the scope of the test paramet