含锌废渣水热硫化浮选回收的工艺研究-有色金属科学与工程.DOC

含锌废渣水热硫化 闵小波1,2，陈杰1，梁彦杰1,2,*，柴立元1,2，张海静1，柯勇1，王延1 （1 中南大学 冶金学院环境工程研究所，湖南 长沙 410083 2国家重金属污染防治工程技术研究中心，湖南 长沙 410083 摘要：以某冶炼废水处理工段所产生的废渣为处理对象，采用水热硫化-浮选工艺对其进行资源化处理。实验首先采用正交实验法对水热硫化的影响因素进行考察，结果认为温度是影响废渣中金属锌（Zn）硫化的主要因素，其次为固液比、反应时间和硫磺添加量最优条件为：硫化时间4 ，温度200 °C，固液比1:3，硫磺添加量18%，在最优条件下废渣中Zn硫化率可以达到90%以上。后续的浮选考察了粒径、抑制剂（CMC）、浮选温度和浮选pH对硫化产物可浮性的影响。研究认为温度是影响人造硫化物浮选的主要因素，最优浮选参数为：粒径38 (m温度 60 ℃CMC: 200 g/t、pH= 8。最优条件下，一次选精矿品可达28.8%的回收率为55.16%。重金属废渣水热硫化 The recovery of zinc from sludge by a combination of hydrothermal sulfidation and flotation Xiaobo Min1,2; Jie Chen1; Yanjie Liang1,2; Liyuan Chai1,2; Haijing Zhang1; Yong Ke1; Yan Wang1 (1 Department of Environment Engineering, School of Metallurgy and Environment, Central South University, Changsha 410083, China 2.Chinese National Engineering Research Center for Control Treatment of Heavy Metal Pollution, Changsha, Hunan 410083, China) Abstract：The present study describes the application of hydrothermal sulfidation and flotation for the metal recovery from the sludge which was produced after the metallurgical waste water treatment. In order realize a higher sulfidation extent, an orthogonal array, L9 (43), was used to examine the effects of four parameters on the sulfidation extent of Zn in the sludge. It suggests that temperature is the most significant factor on the sulfidation of Zn, followed by solid-to-liquid ratio, reaction time and reagent dosage of sulfur. The optimum operating process parameters were established as follows: reaction time (4 h), temperature (200 °C), solid-to-liquid ratio (3:1), the reagent dosage of sulfur (18%). Under these experimental conditions, the sulfidation extent of zinc was greater than 90%. The effects of particle size, depressant dosage (CMC), temperature and pH value on the flotabilities of synthetic ZnS were investigated. The results indicated that temperature was the most important factor on the flotation. Under the optimal conditions (particle size: 38 (m, temperature: 60 ℃, CMC: 200 g/t and p