McMurry FOC7e CH04有机双语.doc

Chapter 4 - Reactions of Alkenes and Alkynes 1. Rank the carbocations below in order of increasing stability (least stable = 1; most stable = 3). Place the number corresponding to the carbocations relative stability in the blank below the structure. ANS: 2. Alkene chemistry is dominated by what type of reaction? a. substitution b. electrophilic addition c. nucleophilic addition d. elimination e. both b and c ANS: B 3. Predict the major organic product(s) in the reaction below. If more than one major organic product is expected, draw each one. ANS:  4. Predict the major organic product(s) in the reaction below. If more than one major organic product is expected, draw each one. Explain the significance of 35?C and ether shown in the reaction. ANS: 35?C and ether are notes related to the reactions conditions. The reaction is carried out at 35?C and the solvent is ether. 5. The following reaction is carried out in cyclohexane with the application of heat. Write the complete equation for the reaction below. If more than one major organic product is expected, draw each one. ANS: 6. What alkene would you use to prepare the following alkyl halide? ANS: Only one alkene would be possible: Instructions: Predict the structure of the alkene you would use to prepare the folloiwng compounds. There may be more than one answer in some cases. 7. Predict: ANS: 8. Predict. ANS: 9. Predict. ANS:  10. Predict. ANS: 11. The product(s) of the reaction when carried out in an organic solvent would be: a. cis-1,2-dibromocyclohexane only b. trans-1,2-dibromocyclohexane only c. 50/50 mixture of cis-1,2-dibromocyclohexane and trans-1,2-dibromocyclohexane only d. mixture with 50% being trans-1,2-dibromocyclohexane only ANS: B Instructions: The reaction of 2-methylpropene with HBr in ether gives one of the two products below. Answer the following question(s) about this reaction. 12. Refer to instructions. The reaction mixture would contain a majority of which