酚二磺酸分光光度法测定水中消酸盐氮的条件控制.pdfVIP

·296 · 价值工程 酚二磺酸分光光度法测定水中硝酸盐氮的条件控制 Determination of Condition Control of Nitrate Nitrogen in Water with Phenol Disulfonic Acid Spectrophotometry 张航① ZHANG Hang ；张宁娟② ZHANG Ning-juan （①宝鸡市环境保护监测站，宝鸡721006 ；②宝鸡市陈仓区环境保护监测站，宝鸡721300） （①Baoji Environmental Protection Monitoring Station ，Baoji 721006 ，China ②Chencang District Environmental Protection Monitoring Station in Baoji City ，Baoji 721300 ，China） 摘要： 对酚二磺酸分光光度法测定水中硝酸盐氮进行了验证性的探讨，结果表明该方法具有测量范围较宽，显色稳定的优点，但 此方法操作繁琐，尤其是对水样的前处理控制不好将对硝酸盐氮含量的测定影响较大。其线性区间在0.02-2.0mg/L 范围内，相关系数 等于0.9999 ，硝酸盐氮浓度小于0.02mg/L 或大于2.0mg/L 时，测量结果将产生一定的误差。 Abstract: This paper verified the method to determine the nitrate nitrogen in water by phenol disulfonic acid spectrophotometry. The results showed that the method had a wide measurement range, and its colour was stable, but its operation is complicated, especially the pre-treatment of the water. If pre-treatment of the water can not be controlled, it will cause greater impact. Its linear range is among 0.02- 2.0mg/L, and the correlation coefficient is equal to 0.9999. When the nitrate nitrogen concentration is less than 0.02mg/L or greater than 2.0mg/L, the measurement results will have a certain margin of error. 关键词： 硝酸盐氮；酚二磺酸法；实验条件控制 Key words: nitrate nitrogen ；phenol disulfonic acid method ；experimental conditions control 中图分类号： 文献标识码： 文章编号： G633.8 A 1006-4311 （2012）30-0296-03 0 引言 烟硫酸充分混合。瓶口插一小漏斗，小心置瓶于沸水浴中 硝酸盐氮是在有氧环境下，亚硝氮、氨氮等各种形态 加热2h ，得淡棕色稠液，贮于棕色瓶中，密塞保存。 的含氮化合物中最稳定的氮化合物，亦是含氮有机物经无 ①如苯酚（C H OH）不纯或有颜色时，应进行蒸馏精