POPs论文：青岛大气中有机氯农药、多氯联苯及7Be的同步观测及时间变化规律.docVIP

POPs论文：青岛大气中有机氯农药、多氯联苯及7Be的同步观测及时间变化规律 【中文摘要】青岛是沿海城市,但气候上更表现为大陆性季风气候,通过对青岛大气颗粒物中的有机氯农药、多氯联苯和大气颗粒物中宇宙射线成因核素7Be进行了为期一年的检测,对其时空变化规律做出初步的推断。对青岛大气颗粒物中HCHs、DDTs和PCBs检测的结果,POPs含量呈夏季少冬季多的趋势。从POPs组成看,虽然在不同采样日各类POP化合物的相对比例不同,但从年度平均来看HCHs、DDTs和PCBs分别占18.4%、27.8%和53.8%,即以PCBs占主导地位。HCHs、DDTs和PCB遵循相同的季节变化趋势,从总体上看呈现同时增大或同时较小的情况,但增大或减小的比例随时间变化并不均匀的。DDTs和PCBs两类化合物之间的同步性要较它们与HCHs的同步性为好。大气颗粒物中POPs含量的变化与某些气象要素的变化有直接联系,降水,风向等要素对其含量影响较为明显,而正常自然温度的变化与大气颗粒物中POPs的含量的高低并没有显著的相关性。青岛市大气颗粒物中7Be浓度高于全球年平均观测值(3.5 mBq/m3),变化范围为1.52～14.58 mBq/m3.最高值出现在2010年4月,最低值出现在2010年7月,年平均值为6.88±0.40mBq/m3,验证了“春季泄漏”现象。影响近地表大气颗粒物中7Be浓度的因素主要为纬度、大气传输、大气清扫效率。大气中7Be以及POPs的浓度变化受气温,降水,风向等多方面的影响,其中以降水的影响比较明显。 【英文摘要】Qingdao is a Coastal city which has a continental monsoon climate.This study of detecting organochlorine pesticides and PCBs in atmospheric TSPs of Qingdao had been on for one year, and also made an preliminary deduce for the temporal change of OCPs and PCBs.By analysing result of detecting the content of HCHs, DDTs and PCBs in Qingdao抯 atmospheric TSPs. POPs content may follow a trends of being less in summer and more in winter. The content of each kind of POPs may be in difference in different day,the average content of the HCHs, DDTs and PCBs in a whole year were 18.4%、27.8% and 53.8%, which is mainly composed by PCBs. HCHs, DDTs and PCBs may follow the same seasonal pattern, which generally increases or decrease at the same time. but the percentage of increase or decrease is not fixed. The content change of POPs in atmospheric TSPs has a directly relation with certain meteorological conditions, such as precipitation, wind direction, and their impact is more obvious.On the contrary,the impact of other meteorological conditions such as tempreture is not so obvious.The average content of Be in Qingdao atmosphere TSP is higher than the world average standard (3.5 mBq/m3), which is 6.88?.40mBq/m3 for Qingdao.The peak happes in April,2010,and the minimum comes out in July,2009,the content flows in the range of