环保型水性聚氨酯胶粘剂的合成及性能研究 Study on Synthesis and Performance of Environmentally-friendly Waterborne Polyurethane Adhesive.pdfVIP
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环保型水性聚氨酯胶粘剂的合成及性能研究 Study on Synthesis and Performance of Environmentally-friendly Waterborne Polyurethane Adhesive
30卷第12期 西部皮革 V01.30No.12
2008年10月 WESTLEAHTER 0tc.2008
环保型水性聚氨酯胶粘剂的合成及性能研究
成丰1,郑海芳1,杨柳涛1,罗琳1,谢秋玉2,李立新p
(DMPA)为主要原料制备了一系列环保型抽『生聚氨酯胶粘剂。讨论了合成条件、DMPA用量、N一甲基吡
咯烷酮(NMP)和三乙醇胺(TELA)对水性聚氨酯乳液及其胶膜性能的影响。实验结果表明:预聚反应温
度为60一75℃,反应时问为4~5h,DMPA含量在3.80.6m珧g可获得比较稳定的乳液。随着DMPA含
量的增加,胶膜吸水率升高,乳液黏度增大,剥离强度先增加后略有下降。当DMPA含量为5.7
mg/kg
时,剥离强度达到最大值,乳液性能最佳。另外,NMP和TELA对乳液和胶膜性能有提高作用。
关键词:水性聚氨酯;胶粘剂;环保型;性能
中图分类号:TS943.4 文献
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