催化氧化法处理难生化炼油污水研究.pdfVIP

5 1 环境 工程学 报 Vol. 5, No. 1 2 0 1 1 1 Ch inese Journal of Environm entalEngineering Jan . 2 0 1 1 侯 钰 高 峰 桑军强 李本高 ( , 100083) , , , , ; , , 22% 848% ; , 135% 106% X7031 A 1673 108( 2011) Treatm ent of refining wastewater by catalytic oxidation H ou Yu Gao Feng Sang Junqiang Li Bengao ( Research Institute of Petroleum Processing, Beijing 100083, China) Abstract The tertiary b iochem ical treated refining w astew ater w as further treated by catalytic oxidation. The resu lts show that the organic m acromolecu les in the refin ing w astew ater are degraded into smaller ones by catalytic oxidation, resu lting in the mi provement of the biodegradab ility. It selectively oxidizes benzyl acid and an iline effectively w ith the removal rate of 2. 2% and 84. 8% , respectively; however, it is less effective to the acetic acid and oxalic acid w ith the removal rate of 135% and 106%, respectively. K ey words w astew ater treatment; catalytic oxidation; m echan ism [ 1] H O H SO ( GR) NaOH ( AR) 2 2 2 4 OH, , : pH , BOD , , [ 2] , 1. 2 , : 200 mL 500 mL , , , , , , 20% NaOH 20% H SO pH 3, 2 4 H O , 30 m in , 2 2 pH , , N aOH pH 8~ , , , 1 h, COD 121 相对分子质量分布 , 022 m , , , , 10 0003 000 1 000, 1 : 200 - 11- 04; : 2010- 01