高性能锂电正极材料LiV3O8-MWCNTs的制备与性能.docVIP

高性能锂电正极材料LiV3O8-MWCNTs的制备与性能 石钏 李永亮 任祥忠 邓立波 高原 张培新 深圳大学化学与环境工程学院 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 利用低温液相法合成了钒酸锂-多壁碳纳米管 (LiV3O8- (w) MWCNTs) (w分别为0、1%、2%、3%、4%和5%) 复合正极材料.采用X-射线衍射 (X-ray diffraction, XRD) 和扫描电镜 (scanning electron microscope, SEM) 对复合材料的晶型和结构进行了表征.XRD分析结果表明, 复合材料仍为单斜晶系;SEM图谱显示, LiV3O8材料附着在MWCNTs的网状结构上, 且使颗粒细化;通过恒流充放电测试、循环伏安 (cyclic voltammetry, CV) 及交流阻抗谱 (electrochemical impedance spectroscopy, EIS) 技术对材料的电化学性能进行了研究, 结果表明, 按LiV3O8质量百分比复合3%MWCNTs的LiV3O8- (3%) MWCNTs复合材料具有最佳的电化学性能, 在0.1 C充放电倍率条件下, 其首次放电比容量为364.5 m Ah/g, 循环50次后放电比容量仍有292.2 m Ah/g, 容量保持率为80.2%, 而纯LiV3O8材料的首次放电比容量为308.2m Ah/g, 循环50次后容量保持率仅为55.4%;采用MWCNTs与LiV3O8复合可使锂离子在材料颗粒间的电荷转移阻抗变小, 有利于Li+的嵌入和脱出. 关键词： 复合材料; 锂离子电池; 低温液相法; 钒酸锂; 多壁碳纳米管; 正极材料; 电化学性能; 作者简介：石钏 (1986—) , 女, 深圳大学实验技术员.研究方向:材料化学.E-mail:shichuan@szu.edu.cn 收稿日期：2017-03-01 基金：国家自然科学基金资助项目 Preparation and properties of LiV3O8-MWCNTs as high performance cathode materials for lithium-ion battery Shi Chuan Li Yongliang Ren Xiangzhong Deng Libo Gao Yuan Zhang Peixin College of Chemistry and Environmental Engineering, Shenzhen University; Abstract： Lithium trivanadate-multiwalled carbon nanotube ( LiV3O8- ( w) MWCNT) ( w = 0, 1%, 2%, 3%, 4%, 5%) composite cathode materials are synthesized by low temperature liquid reaction. The crystal structures and microstructures are investigated by X-ray diffraction ( XRD) and scanning electron microscope ( SEM) . XRD analyses show that the LiV3O8- ( w) MWCNTs are still monoclinic. The SEM images show that the LiV3O8 is attached to the network structure of MWCNTs, and the LiV3O8 particles are refined. The electrochemical properties are also characterized with charge-discharge cycling performance, cyclic voltammetry ( CV) and electrochemical impedance spectroscopy ( EIS) . The results show that LiV3O8- ( 3%) MWCNTs have the best electrochemical properties whenthe mass percentage of MWCNTs is 3 % in the composite, exhibiting a high