3Y-TZP陶瓷的两步烧结法研究.doc

3Y-TZP陶瓷的两步烧结法研究 摘 要 3Y-TZP即为含3%molY2O3的四方多晶ZrO2陶瓷，它是所有氧化锆材料中室温力学性能最高的一种材料，具有高强、高断裂韧性、高耐磨，耐热性、耐蚀性。 本实验采用干压成型后，对含摩尔分数3%Y2O3的ZrO2生坯进行烧结成型，并探讨了常压下单步烧结和两步烧结工艺对其致密化、显微组织和力学性能的影响。通过X射线衍射（XRD）、扫描电镜（SEM）以及材料显微分析等分析手段，分析了3Y-TZP陶瓷的相组成、晶粒大小以及显微组织形貌等。 氧化钇稳定四方氧化锆陶瓷（3Y-TZP）用两步烧结法来控制最后烧结阶段过程中晶粒的生长。单步烧结的3Y-TZP陶瓷相对密度、平均维氏硬度和断裂强度分别为95.99%，11.45GPa和371.30MPa。而3Y-TZP陶瓷经两步烧结烧成后，相对密度、平均显微维氏硬度和断裂强度分别达到96.31%，12.63GPa和330.02MPa。这反映出采用两步烧结法制得的3Y-TZP陶瓷具有更优异的性能。在T1烧结5分钟，坯体密度是94.54%，实现了开口气孔处于不稳定状态，在较低温度（T2）烧结进一步致密，且晶粒长大不明显，得到了平均粒径为0.25μm的3Y-TZP陶瓷。经X衍射分析表明，陶瓷的状态是完全稳定。单步烧结的3Y-TZP陶瓷全部为四方相，粒径是0.35μm。两步烧结陶瓷也仅仅含有2wt%的单斜相。 关键词：3Y-TZP，两步烧结，晶粒生长 Study on two-step sintering of 3Y-TZP Abstract 3Y-TZP for 3%mol yttria stabilized tetragonal zirconia polycrystal ceramics, it was the best one of the all zirconia ceramics on mechanical properties at ambient temperature, with high intensity, high material fracture toughness, fine abrasion resistance, heat resistance and corrosion resistance. In this experiment, 3%mol yttria stabilized tetragonal zirconia polycrystal(3Y-TZP) ceramics compact were sintered after dry extrusion molding. The effects of the single step sintering(SSS) and two step sintering(TSS) on densification, microstructure and mechanical properties were studied. X-ray diffraction(XRD), scanning electron microscopy(SEM) and material microscope were employed to characterize the phases, grain size and microstructure of 3Y-TZP ceramics. Two step sintering (TSS) was applied on yttria tetragonal stabilized zirconia (3Y-TZP) to control the grain growth during the final stage of sintering. Single step sintering 3Y-TZP ceramics relative densities , micro-hardness and fracture intensity were 95.99%, 11.45GPa and 317.30MPa, respectively. But after two step sintering of 3Y-TZP ceramics, of which relative densities ,Vickers hardness and fracture intensity is 96.31%,12.63GPa and 330.02MPa, respectively. The results showed that 3Y-TZP ceramics under the two step sintering present the better performances. Fi