离子液体在混合超级电容器中的应用进展progress-储能科学与技术.pdfVIP

离子液体在混合超级电容器中的应用进展 张之逸,李 曦，张超灿 （武汉理工大学材料学院，湖北 武汉 430070） 摘要：混合超级电容器具有高比功率、高比能量和高循环稳定性等优点，是一种极具潜力的储能装置，但 其常用的溶液电解质或有机电解质分别存在电化学窗口较窄和易燃的缺点，限制了其应用范围。离子液体 具有不可燃性、宽电化学窗口等特点，成为了混合超级电容器用电解质的理想选择。近年来由于对混合超 级电容器与非对称超级电容器定义的理解出现偏差，造成了表述上的混乱，因此尝试对两者的概念进行了 解释和区分。回顾了近年来离子液体在混合超级电容器中的应用，介绍了离子液体单独作为电解液、作为 混合电解液组份、及作为固态电解质组份在混合超级电容器中的应用，指出离子液体高吸湿性与高成本是 目前离子液体在应用过程中需要解决的问题。最后展望了离子液体的未来发展趋势，认为进行离子液体/ 有机溶剂混合电解液的研究，是未来离子液体的研究重点。关键词：离子液体；混合超级电容器；非对称 超级电容器 中图分类号：TK 02 文献标志码：A 文章编号：2095-4239 （2014）00-0000-00 ProgressinApplicationofIonicLiquidsinHybrid Supercapacitor 1 2 2 ZHANGZhiyi ， LiXi ,ZHANG Chaocan SchoolofMaterials ScienceandEngineering,Wuhan University ofTechnology Wuhan430070,Hubei,China （ ， ） Abstract: Hybrid supercapacitors are energy-storage devices with great potential, they typically have high specific power, high cycle stability, high safety and relatively high specific energy,but the aqueous and organic electrolytes they use often suffer from drawbacks such as narrow electrochemical window and high flammability. In the meantime, the unique features of ionic liquids, such as low vapor pressure, non-flammability and wide electrochemical window make them ideal electrolytes for hybrid supercapacitors. Due to the misunderstandings about the notion of hybrid supercapacitor and asymmetric supercapacitor, there has been many inappropriate descriptions about them. In this paper we try to explain the difference between the above-mentioned two kinds of supercapacitors, and review the recent applications of ionic liquids in hybrid supercapacitors, including ionic liquids as pure electrolytes, components for mixture electrolytesand solid electrolytes.It ispointed outthathi