Zn片经水热反应和氟硅烷修饰构建超疏水ZnO表面.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) August A cta Phys. Chim. Sin., 2009, 25(8) ：1593-1598 1593 [Article] Zn 片经水热反应和氟硅烷修饰构建超疏水ZnO 表面 思斯 管自生* 李 强 陆春华 许仲梓 ( 京工业大学材料科学与工程学院, 南京 210009) 摘要： 以乙二胺为溶剂, Zn 片在120 、140 及 160 经水热反应生长出具有蛋糕形、荷叶乳突状、棒状和仙人球 状等微结构的ZnO 表面. 扫描电镜研究表明, 反应时间越长越有利于形成完整的微纳米结构, 反应温度较高生 成的微纳米结构更规整. 140 反应4 h 和160 反应5 h 的ZnO 表面经过氟硅烷修饰后表现出良好的超疏水 性, 与水滴的接触角分别达到154.6毅和157.3毅, 滚动角分别为5毅和3毅. 该方法因其操作简便、成本低廉, 在锌表面 制备特殊微结构和构建超疏水表面具有潜在的应用. 关键词： 水热反应; 超疏水; 氧化锌; Zn 片; 氟硅烷修饰 中图分类号： O647; TG17 Fabrication of Superhydrophobic ZnO Surfaces via Zn Foil Hydrothermal Reactions and Fluoroalkylsilane Modified Process ZHOU Si鄄Si GUAN Zi鄄Sheng* LI Qiang LU Chun鄄Hua XU Zhong鄄Zi (College of Materials Science and Technology, Nanji ng University of Technology, Nanj ing 210009, P. R. China) Abstract ： Cake鄄like, lotus leaf鄄like, trunk鄄like, and cactus鄄like ZnO surfaces grown directly on zinc substrates were fabricated by Zn foil hydrothermal reactions in an ethylenediamine solution at 120, 140, and 160 . Scanning electron microscopy indicated that the micro鄄/submicro complex structures were more regular at longer reaction time and higher reaction temperature. The hydrophobicity of typical structured ZnO surfaces modified with a layer of fluoroalkylsilane were measured. Results showed that the structured surfaces prepared at 140 for 4 h as well as at 160 for 5 h exhibited superhydro