废旧阻燃电脑外壳的热解动力学.PDFVIP

第5卷 第3期 2010 年 3 月 中国科技论文在线 Sciencepaper Online 199 废旧阻燃电脑外壳的热解动力学 陈 源，陈烈强 （华南理工大学化学与化工学院，广州 510640 ） 摘 要：通过对含有四溴双酚A 阻燃剂(tetrabromobisphenol A, TBBPA) 的废旧电脑外壳（红外分析鉴定为丙烯腈-丁 -1 烯-苯乙烯树脂，acryolonitrilr butadiene styrene, ABS）进行热裂解试验和动力学研究，得到不同升温条件下（5 K·min , -1 -1 -1 10 K·min , 20 K·min 和 40 K·min ）阻燃剂分解和塑料裂解的特征温度，以及TBBPA 的阻燃机理。根据Arrhenius定 律和Friedman方法分析研究对象的热解动力学，所得相关系数均在 0.98 以上，TBBPA分解和塑料裂解的活化能分别 为 96.3 kJ·mol-1 和 93.5 kJ·mol-1 。该研究的结果为废旧阻燃ABS塑料的资源化、无害化利用提供可靠的理论参考。 关键词：TBBPA ；ABS ；热解；动力学 中图分类号：X928.7 文献标志码：A 文章编号：1673－7180(2010)03 －0199 －7 Pyrolysis kinetics of flame-retardant waste computer housings Chen Yuan ，Chen Lieqiang (The Key Lab of Enhanced Heat Transfer and Energy Conservation, Ministry of Education, School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: Pyrolysis experiment and kinetic studies were used to investigate the thermochemical characteristics of waste computer housings (acryolonitrilr butadiene styrene(identified with Fourier transform infra-red analysis, ABS) containing tetrabromobisphenol(TBBPA). The decomposition temperatures of TBBPA and cracking temperatures of plastics under different heating rates (5 K·min-1 -1 -1 -1 , 10 K·min , 20 K·min and 40 K·min ) were obtained; the flame-retardant mechanism of TBBPA was clarified. Analyzing the kinetic parameters with Arrhenius law and Friedman method, the correlating coefficients are all above 0.98, activation energy