气相色谱法三重四极杆质谱测定番茄酱中72种农药残留量.PDF

2013, Vol.34, No.12 237 / 72 1 2, * 1 (1. 830063 2. 830052) / 72 SRM QueChers-/ 52000μg/L720.99 3 95.8%80%120%87.5%(RSD)15%(RSN=3) (R μ μ SN=10)0.047.5 g/kg0.112.9 g/kg / Determination of 72 Pesticide Residues in Tomato Paste by TSQ QUANTUMN-GC 1 2, * 1 SHANG De-jun WEI Shuai LI Shi-yu (1. Technique Center of Xinjiang Entry-Exit Inspection and Quarantine Bureau, Ürümqi 830063, China 2. College of Food Science and Pharmaceutical, Xinjiang Agricultural University, Ürümqi 830052, China) Abstract A novel method was developed for the determination of 72 pesticide residues in tomato paste by TSQ QUANTUMN GC (GC-MS/MS) combined with QueChers extraction. Optimal concentrations of standard working solutions, SEM (selected ion monitoring) ion pairs, acquisition time window and collision energy were established for MS/ MS analysis of methamidophos and 71 other pesticides in full scan, daughter ion scan and selected ion scan modes. Over the linear range of 5 to 2000 μg/L, the correlation coeffi cient for each pesticide was bigger than 0.99. Recoveries from spiked samples at three levels indicated that 95.8% of the tested pesticides exhibited a recovery range of 80% to 120% with relative standard deviation smaller than 15% for 87.5% of them. The limits of detection (RSN = 3) varied over the range of 0.04 to 7.5 μg/kg, and limits of quantifi cation (RSN = 10) ranged from 0.1 to 12.9 μg/kg. This method could provide a sensitive, accurate and reilable approach that meets the requirments for quantitative analysis of low levels of pesticides. Key words TSQ QUANTU