聚合物锂离子电池隔膜的研讨.pdfVIP

B013 聚合物锂离子电池隔膜的研究 操建华 朱宝库 徐又一* （浙江大学高分子科学研究所，杭州，310027） 摘 要 采用偏氟乙烯－六氟丙烯无规共聚物 （PVDF-HFP ）为膜材料，N,N －二甲基乙酰 胺（DMAc ）为溶剂，相转化法制备了PVDF-HFP 微孔膜。该膜用1 M 的LiPF6-PC/DMC （体 积比 1：1）电解质液体活化后得到聚合物电解质膜。研究了聚合物浓度和凝固浴组成及温 度等对 PVDF-HFP 微孔膜的结构形态、孔隙率、N2 透气率和吸液率的影响。扫描电镜观察 了各种条件下制得的膜的形态及结构。所得到的PVDF-HFP 膜为非对称膜，孔隙率可达 70 ％，N 2 2 透气率在0.1Mpa 下为306.92 ml/min ·cm ，吸附电解液的能力为自身重量的300 ％， -4 -1 吸液后其室温电导率为9.02 ×10 S cm 。 关键词 聚（偏氟乙烯－六氟丙烯） 相转化 锂离子电池 隔膜 Study on the polymer microporous membranes for lithium ion battery separator CAO Jianhua, ZHU Baoku, XU Youyi (Institute of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, Zhejiang, China) Abstract The PVDF-HFP microporous membrane was prepared by phase inversion method (using DMAc as solvent), then activated by 1M LiPF6 in EC/DMC (1: 1, v/v) electrolyte solution. The effect of polymer concentration, composition of coagulation bath and temperature on membrane morphology, porosity and electrolyte liquid uptake were investigated. The surface and cross section structure of membranes were observed by SEM. The porosity of membranes is up to 70% and the permeability of 2 N2 is 306.92 ml/min ·cm at 0. 1MPa.The liquid uptake is 300wt% of its weight. Gel polymer electrolyte composed of PVDF-HFP-based microporous membrane, LiPF6-EC/DMC show high ionic -4 -1 conductivity and can reach to 9.02 ×10 S cm at room temperature. Keywords Poly (vinyldiene fluoride-co- hexafluoropropylene), phase inversion, lithium ion battery, separator 引 言 随着能源、信息、材料的发展，二次锂离子电池技术及其相关材料也得到迅速发展。聚合 物锂离子电池与目前使用的液态锂离子电池相比，具有体积小、质量轻、寿命长、安全性能高 及易于电池形状设计等特点，可满足手机和笔