CH3COOOHH2O2液相氧化脱除烟气中砷的实验研究.docVIP

CH3COOOH/H2O2液相氧化脱除烟气中砷的实验研究 赵毅 仇稳 马宵影 王佳男 华北电力大学环境科学与工程学院 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 针对环境中的砷污染对人体健康的影响, 以CH3COOOH/H2O2溶液作为吸收剂, 在自行设计的小型鼓泡反应器中进行了烟气脱砷的实验研究.考察了H2O2浓度、过氧乙酸投加量和模拟烟气成分等因素对烟气脱砷效率的影响.结果表明, 在H2O2浓度为0.2mol/L, CH3COOOH投加量为0.04mol/L, 溶液pH值为5.5, 吸收液温度为50℃时, 脱砷效率可达100%.采用高效液相色谱-氢化物发生-原子荧光联用技术 (HPLC-HG-AFS) 对液相离子产物进行了定性与定量检测, 脱砷产物主要为As (V) . 关键词： 环境科学; 过氧乙酸; 过氧化氢; 氧化吸收; 烟气; 作者简介：赵毅 (1956-) , 男, 河北秦皇岛人, 华北电力大学教授, 博士生导师, 主要从事大气污染控制研究, E-mai:qqqiuwen@163.com.华北电力大学环境科学与工程学院教授, 博士生导师, 中国电机工程学会电力环保专业委员会副主任、国家烟气脱硫工程中心学术委员会委员、国际二氧化碳封存风险评估委员会委员.主要从事烟气脱硫、脱硝、脱汞、二噁英脱除和二氧化碳捕集和利用等方面的研究.已发表学术论文400余篇, 其中SCI收录引用100余篇, 主持国家863计划、973计划和国家自然科学基金项目等20余项科研课题.曾获霍英东青年教师奖, 全国电力系统劳动模范, 全国模范教师. 收稿日期：2017-04-12 基金：国家863计划资助项目 (2013AA065403) Experimental Study on the Removal of Arsenic from Flue Gas by CH3COOOH/H-2O2 Oxidation Method Zhao Yi Qiu Wen Ma Xiaoying Wang Jianan School of Environmental Science and Engineering, North China Electric Power University; Abstract： Aim at the arsenic pollution in the environment on human health, with CH3COOOH/H2O2 reagent as the absorbents, the experimental study on the removal of arsenic in flue gas by CH3COOOH/H2O2 oxidation process were carried on in the self-designed bubbling reactor.The influence of H2 O2 concentration, dosage of CH3 COOOH, SO2 concentration, NO concentration, oxygen content and carbon dioxide conctent on the removal of arsenic was studied, respectively.The optimum operating parameters were:the concentration of H2 O2 was 0.2 mol/L, dosage of CH3 COOOH was 0.04 mol/L, the pH value of the absorbent was 5.5, the reaction temperature was 50℃.Under optimal conditions, the removal efficiency of arsenic reach100%.Meanwhile, based on the qualitative and quantitative detection of related ions in solution by high-performance liquid chromatography-hydride generation-atomic fluorescence spectrometer (HPLC-HG-AFS) .The As (V) is the main product of arsenic removal. Keyword： envi