新型空调蓄冷材料四丁基溴化铵-水相变条件和相变热实验研究.doc

新型空调蓄冷材料四丁基溴化铵-水相变条件和相变热实验研究 第3O卷第5期 2009年10月 制冷 JournalofRefrigeration Vo1.30.No.5 October2009 文章编号:0253-4339(2009)05—0024—03 DOI编码:10.3969/j.issn.0253—4339.2009.05.024 新型空调蓄冷材料四丁基溴化铵一水 相变条件和相变热实验研究 孙志高工江承明孙立 (1.苏州科技学院环境科学与工程学院苏州215011;2.中山大学工学院广州510275) 摘要四丁基溴化铵水溶液在适当的浓度范围内可在常规空调冷冻水温区内发生固一液相变,形成半笼水合物,是一种潜 在的空调蓄冷理想材料.利用实验室的水合物形成实验装置测量了四丁基溴化铵水溶液固一液相变条件,实验结果表明当 溶液的质量浓度低于45%时,相变温度随着溶液浓度的增大而增大,但当溶液浓度超过25%,相变温度增加的幅度减小. 四丁基溴化铵水溶液的浓度超过45%后,其固一液相变温度反而下降.利用DSCN量了四丁基溴化铵水溶液的相变热,相变 热达~1J195.9kJ/kg. 关键词工程热物理;蓄冷:相变条件;相变热;四丁基溴化铵 中圈分类号:TK02;TB612文献标识码:A ExperimentonPhaseChangeConditionsandPhaseChangeLatentHeatof Tetra—n—butylAmmoniumBromideAqueousSolutionsforColdStorage SunZhigaoJiangChengmingSunLi (1.SchoolofEnvironmentalScienceandEngineering,SuzhouUniversityofScienceandTechnology,Suzhou 215011,China;2.Schoolofengineering,SunYat-SenUniversity,Guangzhou,510275,China) AbstractTetra一一butylammoniumbromide(TBAB)aqueoussolutioncanformsemi—clathratehydrateatsuitablesolution concentrationandtemperatureofchilledwateratatmospherepressure.Itisapotentialsolid—liquidphasechangematerialforcold storageinairconditioningsystems.Thesolid—liquidphasechangeconditionsofTBABaqueoussolutionswereexperimentally measuredusingthetestrigforhydrateformation.TheexperimentalresultsshowthatthephasechangetemperatureoftheTBAB hydrateincreasedwiththeincreaseoftheconcentrationoftheTBABaqueoussolutionwhenthesolutionconcentrationwaslessthan 45%,buttheincrementofthephasechangetemperaturedecreasedwhentheTBABsolutionmassfractionexceeded25%.Thephase changetemperatureoftheTBABhydratedecreasedwiththeincreaseintheconcentrationoftheTBABaqueoussolutionwhenthe solutionconcentrationwasmorethan45%.ThephasechangelatentoftheTBABaqueoussolutionwasmeasuredusingtheDSCrig andthetestresultshowsthatthephasechangelatentwasabout195.9kJ/kg. KeywordsEngineeringthermophysics;Coldstorage;Phasechangeconditions;Phasechangelatentheat;Tetra一一butylammonium bromide 随着经济和社会的持续发展,工业和居民用 电量越来越大,我国电网的负荷和峰谷差也 越来越大,每到夏天用电高峰季节拉闸限电的现象 时有发生,严重影响了工业生产和人民的生活.