静电纺丝制备Eu(BA)3phenPANIPVP光电双功能复合纳米纤维及其性能.PDFVIP

See discussions, stats, and author profiles for this publication at: /publication/2863047 7 Electrospinning preparation and properties of Eu(BA) 3phen/PANI/PVP luminescence- electricity ifunctional composite... Article in Chemical Journal of Chinese Universities -Chinese Edition- · August 2012 DOI: 10.3 6 /j.issn.0251-07 0.2012.08.005 CITATIONS READS 18 5 5 authors, including: Wang Jinxian Changchun University of Science and Technology 250 PUBLICATIONS 2,322 CITATIONS SEE PROFILE Some of the authors of this publication are also working on these related projects: Electrospinning nanocomposites View project Li-ion Batteries, especially cathodes materials View project All content following this page was uploaded by Wang Jinxian on 31 October 2016. The user has requested enhancement of the downloaded file. Vol.33 高等 学校 化 学 学报 No.8 2012年8月 摇 摇 摇 摇 摇 摇 CHEMICALJOURNAL OF CHINESE UNIVERSITIES摇 摇 摇 摇 摇 摇 1657 ~1662 静电纺丝制备Eu(BA) phen/ PANI/ PVP 3 光电双功能复合纳米纤维及其性能 王莹熇,王进贤,董相廷,于文生,刘桂霞 (长春理工大学应用化学与纳米技术吉林省高校重点实验室,长春 130022) 摘要摇 采用静电纺丝技术将聚苯胺(PANI)和稀土配合物Eu(BA) phen掺杂到高分子材料聚乙烯吡咯烷酮 3 (PVP)中,制备出新型的具有光电双功能的Eu(BA) phen/ PANI/ PVP复合纳米纤维. 采用扫描电子显微镜、 3 X射线能量色散谱仪、荧光光谱仪及宽频介电松弛谱仪对样品进行了表征. 实验结果表明,复合纳米纤维直 径为(270依31) nm. 在275 nm紫外光激发下,Eu(BA) phen/ PANI/ PVP复合纳米纤维发射出主峰位于580, 3 3+ 5 7 5 7 5 7 594 和617 nm 的红光, 对应于 Eu 的 D 寅 F , D 寅 F 和 D