Thermophysical properties of Sm2(Zr(1-x)Cex)2O7 ceramics.pdfVIP

Thermophysical properties of Sm2(Zr(1-x)Cex)2O7 ceramics.pdf

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Thermophysical properties of Sm2(Zr(1-x)Cex)2O7 ceramics

RAREMETALs VoL28,No.3。Jun2009,p。226 DoI:10.1OO7,s12598.009.OO44.0 ThermophysicalpropertiesofSm2(Zrl_xCex)207ceramics ZHANGHongsong,SUNKun,XUQiang。,WANGFuchi。,LIULing。,WEIYuan, andCHENXiaoge DepartmentofMechanicalEngineering,HenanInstituteofEngineering,Zhengzhou450007,China DepartmentofPhysicsandElectronics,ChuxiongUniversity,Chuxiong675000,China 。SchoolofMaterialsScienceandEngineering,BeijingInstituteofTechnology,Bejiing,100081,China Received12July2008;receivedinrevisedform 23December2008;accepted25December2008 Abstract Sm2(Zrl— 207 =0.1,0.2,and0.3)ceramicswerepreparedbysofidreactionmethodat1600。Cfor10husingSm203,ZIO2,andCeO2 asstartingreactants. phasecompositions,microstructures,htermalexpnasioncoefficients,andpartialhtemr al conductivitiesofhtese materialswereinvestigatde.X.raydiffraction(XRD)resultsrevealhtatSm2(Zro9Ceo1)207wihtpyrochlorestructurenadSm2(Zrl ex)207 = 0.2and0.3)wihtfluoritestructureweresynhtesized,andscanningelectricalmicroscopy(SEM)imagesshowthathtemicrostructuresof theseproductsaleverydense.Thelinerahtemr al expansioncoemcientsnicreasewiht increasnigtemperaturenihtetemperaturerangefrom ambientto1200~C,nadhtehtemr al expnasioncoefficientsincreasewiht increasnigcontentofdopde CeO2.The血emr al conductivitiesof Sm2(Zr0.sCeo.2h07nadSmz(Zro.7Ceo.3)207decreasegraduallywihtna increaseintemperature.Theseresultsshowhtathtesynthesizedce- ramicmaterialscna beexploredas novelprospectivecandidatematerialsofruseinnewhtermalbarriercoatingsystemsinhtefuture. Keywords:solidstatereaction;X—raymehtods;htemr alexpnasion;htermalbarriercoatings lowingrequriements,suchasasatblephase,low htermal 1.Introduction conductivity,highhtemr al expnasioncoefficient,chemical Higheroperatingtemperaturesofturbineenginesresultin resistnace,low sintefingrate,nadhighfracturetoughness lowerfuelconsumption.h

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