负载V和Ag的中孔和微孔分子筛对生物质与废轮胎共热解油性质影响的比较研究.pdf

中国工程热物理学会 燃烧学 学术会议论文 编号：084039 负载V和Ag的中孔和微孔分子筛对生物质 与废轮胎共热解油性质影响的比较 1，2 2 1 1 曹 青 ，高永强 , 鲍卫仁 , 吕永康 (1. 太原理工大学煤科学与技术教育部山西省重点实验室 山西 太原 030024 2. 太原理工大学化工学院 山西 太原 030024) （Tele: E-mail: qcao2000@163.com） 摘 要 ：在500 ℃下将不同比例的木屑与废轮胎混合物在V/SBA-15 、V/HZSM-5 和Ag/SBA-15 、 Ag/HZSM-5催化作用下共热解，研究了不同催化剂和不同比例的木屑与轮胎混合物对热解油产率、热 值、粘度及对铜片腐蚀性、元素组成等性质的影响。结果表明，热解油产率和热值均随着轮胎比例增 大而增加，而比重和粘度在降低。当木屑在混合物中质量低于40 wt% 时，采用Ag/HZSM-5 、Ag/SBA-15 和V/HZSM-5作催化剂得到的共热解油粘度和比重达到0#柴油对粘度和比重的要求；铜片腐蚀性表明， 共热解油对铜片试验前后质量变化在0.9985%-0.9998%之间，表面没有明显变化，腐蚀性达到燃料油要 求。 关键词： SBA-15 热解油；共热解；生物质；废轮胎；催化 COMPARISON ABOUT THE OIL PERPERTIES FROM CO-PYROLYSIS OF BIOMASS AND TYRE WITH CATALYSTS MIROSIEVE AND MESOSIEVE-LOADED SILVER AND VANADIUM 1, 2 2 1 1 CAO Qing , GAO Yong Qiang , BAO Wei-Ren , LV Yong-Kang (1. Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China 2. College of Chemistry and Engineering, Taiyuan University of Technology, Taiyuan 030024, China) Abstract: The mixtures composing of different proportional saw dust and tyre under different catalysts such as V/SBA-15、V/HZSM-5and g/SBA-15 、Ag/HZSM-5 were co-pyrolyzed at 500 ℃ in the experiments. The influence of types of catalysts and the ratio of saw dust to tyre on pyrolytic oil yield, high heating value (HHV) , viscosity and the cautery of copper and the elementary composition of oil were investigated. The results showed that, there was an increase in the pyrolytic oil yield and HHV but decrease i