采用固化复合吸附剂的吸附式低温冷冻系统的性能研讨.pdf

研究论文 采用固化复合吸附剂的吸附式 低温冷冻系统的性能研究 李廷贤，王如竹，陈恒，王丽伟，吴静怡 (上海交通大学制冷与低温工程研究所, 上海 200240) 摘要：设计了一种以氯化锰—氨为吸附工质对的化学吸附式低温冷冻系统，利用膨胀石墨的多孔特性作为复合反应物的添 加剂来提高吸附剂的传质性能，同时采用压块固化技术以提高吸附剂的传热性能。实验结果表明，膨胀石墨的添加有效防 止了吸附剂的结块和吸附性能的衰减，复合吸附剂吸附量高达0.47 kg ⋅ kg − 1 ；吸附剂与制冷剂之间的化学反应对吸 NH Salt 3 附床温度的变化有较大影响，蒸发温度不同导致吸附剂的吸附平台温度不同，且蒸发温度越低，吸附剂吸附合成反应速率 越低；当蒸发温度从-35 °C 上升到 0 °C 时，单位质量吸附剂制冷功率SCP (Specific Cooling Power) 从206 W·kg-1 增大到 706 W ·kg-1 。冷却水温度为25 °C 、蒸发温度为-30 °C 时，采用该固化复合吸附剂的吸附式低温冷冻系统SCP 和COP 分别 高达350 W ·kg-1 和0.34 。 关键词：化学吸附制冷；低温冷冻；固化复合吸附剂；传热 中图分类号：TQ 025 文献标识码：A 文章编号：N104 Performance study of a sorption deep-freezing system using consolidated composite adsorbent LI Tingxian, WANG Ruzhu, CHEN Heng, WANG Liwei, WU Jinyi (Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai 20030, China) Abstract ：A chemisorption deep-freezing system using manganese chloride-ammonia as sorption working pair was designed. For this test unit, expanded graphite was used as the porous medium of composite reactant to improve the mass transfer inside adsorbent, and the consolidation technology was utilized to enhance the heat transfer. Experimental results showed that the additives of expanded graphite can avoid the agglomeration and the attenuation of sorption capacity. The consolidated composite adsorbent could uptake 0.47 kg ammonia per kg reactive salt. The chemical reaction between the composite adsorbent and refrigerant has a strong influence on the temperature