盐酸介质中复配缓蚀剂对N80钢缓蚀效果分析研究.docVIP

盐酸介质中复配缓蚀剂对N80钢缓蚀效 果分析研究 胡军王甜甜王祯樊安郑茂盛 西北大学化工学院南洋理工大学材料科学与工程学 篋西北大学载能技术与应用研宄所 针对N80钢在盐酸溶液中的腐蚀，利用曼尼希碱与钨酸钠复配缓蚀剂作为盐酸 溶液中N80钢的缓蚀剂，通过X射线光电子能谱、电化学实验分析研究了 N80 钢在不同配比缓蚀剂中的缓蚀行为。研究结果表明，曼尼希碱与钨酸钠缓蚀剂复 配使用后，随着配比的增大，腐蚀电流密度逐渐减小，容抗弧半径逐渐增大， 当曼尼希碱与钨酸钠缓蚀剂浓度均为0.000 2mol/L （配比为1 : 1）时，缓蚀效 率最高。微观分析表明，缓蚀剂复配后k2p结合能均大于单独使用两种缓蚀剂 时的结合能，表明复配后钨酸钠缓蚀剂在N80钢表面形成的沉淀膜可以有效弥 补N80钢在曼尼希碱吸附膜中的空隙，两者结合形成了致密的膜层，有效提高 了缓蚀效率。 关键词： N80钢;缓蚀剂;复配;X射线光电子能谱;电化学实验; 胡军（1982-）,男，陕丙丙安人，副教授，傅士，从事腐蚀与防护 研究工作。 收稿曰期:2017-05-30 基金：W家自然科学基金 Corrosion Inhibition Effect Research of Compound Corrosion Inhibitor for N80 Steel in HC1 Solution Medium HU Jun WANG Tian-tian WANG Zhen FAN An ZHENG Mao-sheng Northwest University， School of Chemical Engineering; Northwest University，a. School of Chemical Engineering; Abstract： The behavior of compound corrosion inhibitors was investigated based on X-ray photoelectron spectroscopy and electrochemical experiment. Mannich base and sodium tungstate were compounded as corrosion inhibi tors. A series solution concentration and combine proportion was used for both Mannich base and sodium in the research. The results indicated that along with the increasing of the proportion, the corrosion current density decreases while the capacitance arc radius increases gradually. When the Mannich base and sodium tungstate concentration are bothO. 000 2 mol/L and combined in a ratio of 1 : 1，a maximum corrosion efficiency was obtained.In addition, microscopic analysis showed that compound corrosion inhibitor owns Fe2 p binding energy larger than that the two single corrosion inhibitor either.It illustrated that sodium tungstate precipitation had effectively filled the lap in the Mannich base adsorption film and formed a dense film on N80 steel material surface, and an enhanced corrosion inhibition efficiency was obtained. Keyword： N80steel; inhibitor; compound; X-ray photoelectron spectroscopy; electrochemical experiment; Received： 2017-05-30 N80钢是一种常用的石油套管材料，常被用于油气开采和输送，使用时往往处 于高温、高压或C02、H2S酸性气体、C1等环