石墨烯掺杂聚砜基正渗透膜的结构和性能.docVIP

石墨烯掺杂聚砜基正渗透膜的结构和性 能 胡念左浩然付佳葰吕慧童奕皓刘慧清亶贵r 华东理工大学化学工程联合国家重点实验室 采用相转化法分别制备丫掺杂有石墨、石墨烯和氧化石墨烯的聚砜正渗透（F0） 膜支撑层，通过间苯二胺和均苯三甲酰氯间的界而聚合在支撑层表而制备了聚 酰胺活性层。采用扫描电子显微镜（SEM）表征膜表面和断面的结构形貌，测定 膜孔隙率和亲水性，考察不同掺杂物时1^0膜的性能。结果表明，掺杂石墨烯和 氧化石墨烯，支撑层断面结构更加疏松，孔隙率和纯水透过常数（PWP）明显增 加，制备的相应F0膜性能得到改善，水通量增大。掺杂石墨则导致支撑层上表 而变粗糙，断而结构密实，其孔隙率减小，PWP值降低，膜性能变差。其中，掺 杂了氧化石墨烯的F0膜表现出最好的性能，水通量在活性层朝向驱动液侧 （AL-DS）模式下可达37. 10L/ （m2Xh）,相比无掺杂F0膜增加了 38. 7%。 关键词： 氧化石墨饰;掺柴;正渗透;膜；结构;性能; 胡念（1992—），女，研宂生，研宂方向为正渗透。 E-mail:hul8702151940@163. com。 曹贵平，教授，研究方向为聚合物、催化剂和复合材料等。 E-rnail:gpcao@ecust. edu. cn。 2017-03-22 基金：上海市教育委员会科研创新重点项目（14ZZ062） Structure and performance of forward osmosis membranes based on polysulfone substrates incorporated with graphene HU Nian ZUO Haoran FU Jiabei Lt) Hui TONG Hhao LIU Huiqing CAO Guiping State Key Laboratory of Chemical Engineering， East China University of Science and Technology; Abstract： Polysulfone supporting layers incorporated with graphite (GI)，graphene (GE) ， and graphene oxide (GO) were respectively prepared by phase inversion method. Then the polyamide active layers were prepared via interfacial polymerization of m-phenylenediamine and trimesoyl chloride on the supporting layers. The morphologies of top surface and cross section of the membranes were characterized by SEM. The porosity, hydrophilicity and performance of FO membranes with different incorporated additives were investigated. The results showed that the structures of the cross section of the supporting layers incorporated with GE or GO were looser, resulting in increased porosity and pure water permeability (PWP) constant. Thus the properties of corresponding FO membranes were improved. However, the incorporating of Gl resulted in the prepared membrane with rough surface, dense cross section, lower PWP constant, and worse performance. The FO membrane prepared on the supporting layer incorporated with GO exhibited the best performance. The water flux reached 37. 10 L/ (mJXh) under the AL-DS membrane orientation, increased by 38.