石墨烯负载镍催化CO2加氢甲烷化.docVIP

石墨烯负载镍催化C02加氢甲烷化 张荣斌仝塞杨金美唐纤秣黄传庆王学文冯刚 蔡建信 南昌大学化学学院应用化学研宄所南昌大学资源环 境与化工学院 采用改进的Hummers法制备了氧化石墨烯（GO），经水合胼还原得到石墨烯 （RGO）,通过浸渍法制备了石墨烯负载的镍基催化剂（Ni/RGO）;对其催化二氧 化碳甲烷化反应的性能进行了研究，并与以碳纳米管（CNTs）和活性炭（八C） 为载体负载的Ni基催化剂进行丫比较.由于催化剂的载体分别为RGO, CNTs和 AC,所以Ni将会表现出不同的形态.利用红外光谱（FTIR）、比表而积（BET） 测试、程序升温还原（H2-TPR）、X射线衍射（XRD）分析和透射电子显微镜 （TEM）等表征手段对其结构及物理性质进行了表征.结果表明，Ni/RGO具有相对 较大的比表面积（316 m7g） , Ni在Ni/RGO上的颗粒尺寸（5. 3 nm）小于其在 Ni/CNTs （8.9 nm）和Ni/AC （11.6 nm）上的颗粒尺寸;该催化剂在二氧化碳甲 烷化反应中具有更高的催化活性和选择性，而且具有良好的使用寿命. 关键词： 石墨焼;碳纳米管;活性炭;C02加氢;银催化剂; 蔡建信，男，，副教授，主要从事无机纳米材料及能源催化方面 的研究.E-mail:cjx@ncu. edu.cn 2017-06-06 基金：国家自然科学基金（批准号资助 Graphene Supported Nickel Catalyst for Methanation of Carbon Dioxide ZHANG Rongbin TONG Sai YANG Jinmei TANG Xiannong HUANG Chuanqing WANG Xuewen FENG Gang CAI Tianxin Institute of Applied Chemistry, College of Chemistry, Nanchang University; School of Resources Environmental and Chemical Engineering, Nanchang University; Abstract： Graphene oxide (GO) was prepared from purified natural graphite via the modified Hummers method, and hydrazine hydrate reduced graphene oxide supported nickel catalysts were prepared via impregnation method. The influence of different supports of Ni-based catalysts for the carbon dioxide methanation reaction was investigated. Using reduced graphene oxide (RGO) ， carbon nanotubes (CNTs) and activated carbon (AC) as supports, nickel catalysts with different morphologies were formed. The prepared samples were characterized by FTIR, BET, H2~TPR, XRD and TEM techniques and applied in carbon dioxide methanation. The results reveal that Ni/RGO has a relative large specific surface area (316 m2/g) ? The particle size of nickel on Ni/RGO (5- 3 nm) is smaller than that on Ni/CNTs (8. 9 nm) and Ni/AC (11. 6 nm) . Ni/RGO shows better catalytic activity and selectivity of carbon dioxide methanation reaction than that on Ni/CNTs and Ni/AC. Ni/RGO catalyst has a remarkable stability. Keyword： Graphene; Carbon nanotubes; Activated carbon; C02 methanati