不同掺杂浓度对Al2O3Cr光电特性的影响.doc

分类号： U D C：D10621-408-(2011)2925-0 密 级：公 开 编 号： 不同掺杂浓度对Al2O3:Cr光电特性的影响 论文作者姓名： 何健钊 申请学位专业： 应用物理学 申请学位类别： 工学学士 指导教师姓名（职称）： 杨维清(讲师) 论文提交日期： 2011年06月10日 不同掺杂浓度对Al2O3:Cr光电特性的影响 摘 要 氧化铝陶瓷具有绝缘、高机械强度、耐高温的性质，氧化铝也可做成透明陶瓷、生物惰性陶瓷等功能材料。本文介绍了掺Cr氧化铝陶瓷的制备流程，采用固相烧结法制备了3组浓度分别为0.641wt%、3.258wt%、6.635wt%的Cr掺杂Al2O3样品，通过X射线衍射仪(XRD)、荧光分光光度计、四探针测试仪的测试，分析了掺杂不同浓度Cr对氧化铝陶瓷光学、电学性能的影响。研究发现3组样品都显示出上转换发光特性；Cr3+掺杂浓度越高，样品的荧光发射强度越低；在400～500nm激发波长范围内，0.641wt%样品共测得5个发射峰，其中691nm处的发射峰最尖锐，3.258wt%样品也在691nm处测得发射峰，6.635wt%样品在220～320nm激发波长范围内在356nm和709nm处有发射峰；提高Cr3+的掺杂浓度可降低Al2O3的烧结温度；烧结后样品的致密度在3.258wt%的掺杂浓度处最小；掺杂浓度对晶面间距的影响甚微；随着掺杂浓度的增加，样品的平均电阻率呈逐渐降低的趋势。迄今发现利用氧化铝制成的陶瓷具有许多优异性能，使氧化铝陶瓷逐渐成为研究热点。 关键词：Al2O3陶瓷；Cr掺杂；浓度；固相烧结法；光电特性 The Influence of Various Doping Concentration on Photoelectric Properties of Al2O3: Cr Abstract Alumina ceramics has high mechanical strength, insulation, high temperature resistant properties, also can make it as function material like transparent alumina ceramic, biological inert ceramics, and so on. In this article, the preparation of alumina ceramics doped with Cr process have been described and a concentration of three groups, namely, 0.641wt%, 3.258wt% and 6.635wt% of the Cr doped Al2O3 sample have been prepared. Through X-ray diffraction (XRD), four-probe meter test and Spectrofluorophotometer, it analyzes optical properties and electrical properties of doping Cr with alumina ceramics. Three samples show that up-conversion luminescence properties. The higher Cr3+ doped concentration, the lower fluorescence emission intensity. In the excitation wavelength 400 ~ 500nm range, 0.641wt% sample has five emission peaks. There are the most strong emission peaks of both 0.641wt% and 3.258wt% at 691nm. Two emission peaks of the 6.635wt% sample are, respectively, 356nm and 709nm, in excitation wavelength range 220 ~ 320nm. Increasing the concentration of Cr3+ in Al2O3 can reduce the sintering temperature. Sintered density of samples increased w