CO2在铜掺杂的TiO2纳米管中的光催化还原研究.DOCVIP

C02在铜掺杂的TiO2纳米管中的光催化 还原研究 张宏忠张钰叶长明王明花秦小青李华中 郑州轻工业学院材料与化学工程学院中国轻工业污 染治理与资源化重点实验室环境污染治理与生态修 分别通过阳极氧化法和电沉积法制备了门02纳米管及铜掺杂的TiO2纳米管 (CuxOy/TiO:纳米管)复合材料。利用X射线粉末衍射仪、扫描电子显微镜和X 射线能谱分析等手段对材料进行表征。结果表明：用阳极氧化法制备的Ti02纳米 管为锐钛矿型，平均管直径为90110?，平均管长为300?左右;采用电沉积法 制备的CuxOy/TiO2纳米管中铜以CuO的形式存在。在密封悬挂式光催化系统中， 研究不同浓度CuSO4电镀液制备的CuO/TiOjft米管对C02的光催化还原行为。在 500W氙灯光照的条件下，Ti02纳米管和Cu0/Ti02纳米管还原(：02的产物是CO和 CH,;TiO2纳米管在光照6h时，CH：的产率达到1.3X10 7 (cm2 ? h),而0.04mol/L CuS04电镀液制备的CuO/TiO2纳米管在同样条件下，CH4的产量达到3. 7X 10 7 (cni2*h)。这说明CuO/TiO2纳米管显著提高了 C02的光催化还原效率。 关键词： 铜掺杂;Ti02纳米管;光催化;还原;C02; COj.甲烷; 基金：河南省高校科技创新人才支持计划(2013IIASTIT031) Copper-doped Ti02 nanotube:characterization and photocatalytic reduction activity for C02 Zhang Hongzhong Zhang Yu Ye Changming Wang Minghua Qin Xiaoqing Li Huazhong School of Material and Chemical Engineering， Zhengzhou University of Light Industry; Abstract： By using the methods of anodic oxidation and electrodeposition, TiO2 NTs and copper-doped TiO2 NTs (CuxOy/TiO2 NTs) were prepared, respectively. The obtained Ti02 NTs and Cux0y/Ti02 NTs were characterized by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. The results showed that Ti02 NTs prepared by anodic oxidation were in anatase type with average tube diameter of 90 nm to 110 nm and average length of about 300 nm. As well as the copper in Cux0y/Ti02 NTs prepared by electrodeposition was in the form of CuO. In a sealed photocatalytic system, the photocatalytic reduction activity of CuO/TiO2 NTs for C02 was investigated. Under the condition of UV light, both Ti02 NTs and CuO/TiO2 NTs can reduce C02 into CO and CH.,. The production rate of CIli with Ti02 NTs and Cu0/Ti02 NTs (prepared in the plating solution of 0. 04 mol/L CuSOi) was 1. 3X 10 V (cm2 ? h) and 3. 7X 10 V (cm2 ? h) during 6 h UV light, respectively. Therefore, CuO/TiO2 NTs can significantly improve the efficiency of photocatalytic reduction for C02. Keyword： copper-doping; Ti02 NTs; photocatalysis; reduction; carbon dioxide; c