KH560修饰纳米硅溶胶对铁铬黑建筑节能涂料性能的影响.DOCVIP

KH560修饰纳米硅溶胶对铁铬黑建筑节 能涂料性能的影响 杨光邓安仲 中国人民解放军陆军勤务学院 采用水浴加热法以硅烷偶联剂KII560修饰纳米硅溶胶，然后与纯丙乳液混合， 制备了铁铬黑建筑节能涂料。采用傅里叶变换红外光谱仪和扫描电镜表征了修饰 前后硅溶胶粉末的结构和微观形貌，采用紫外/可见/近红外分光光度计、红外发 射率测量仪、精密色差仪、接触角测量仪和氙灯老化箱，探讨了改性硅溶胶用量 对涂层性能的影响。增大改性硅溶胶用量虽然可以增强涂层的反射性能，提升涂 层的耐人工老化性和耐沾污性，但过多的改性硅溶胶会导致成膜困难，反而降 低涂层的性能。当改性硅熔胶与纯丙乳液的质量比为1:1时，所制涂层的综合性 能最好:相比未添加改性硅溶胶的涂层，其太阳光反射比和近红外反射比分别提 高了 7. 41%和8. 33%,老化和污染后的太阳光反射比变化率则降低了 2. 67%和 1.30%,静态水接触角增大了 29.2°，耐水性、附着力、铅笔硬度、柔韧性和冲 击强度均得到了一定程度的提升。 关键词： 建筑节能涂层;纯丙乳液;硅溶胶;改性;硅烷偶联剂;太阳光反射比;耐老 化性； Effect of KH560-modified nano-silica sol on properties of energy-efficient architectural coating with iron chrome black as pigment YANG Guang DENG An-zhong Army Logistics University of PLA; Abstract： The surface of silica sol was modified by silane coupling agent KII560 in a heated water bath, and the modified silica sol was then blended with pure acrylic emulsion to prepare an energy-efficient architectural coating material with iron chrome black as pigment. The structure and micro-morphology of silica sol particle before and after modification were characterized by Fourier-transform infrared spectrometer and scanning electron microscope. The effect of the content of modified silica sol on properties of the coating obtained therewith was studied by ultraviolet/visible/near infrared spectrophotometer, infrared radiometer, precision colorimeter, contact angle meter and xenon arc lamp weatherometer. The reflection performance of the coating is enhanced and its resistance to artificial aging and stain leveled up with the increasing of modified silica sol content. However, excess amount of modified silica sol leads to a difficulty in film-forming and degradation of coating properties. The coating prepared with modified silica sol and pure acrylic emulsion at a mass ratio of 1:1 has the best comprehensive performance, as shown by higher solar reflectance (increased by 1. 41%) and near infrared reflectance (increased by 8. 33%)，lower solar reflectance variation after aging (declined by 2. 67%)