SO42-Fe2O3-TiO2光催化剂制备及对染料废水光活性研究.DOCVIP

SO42-/Fe2O3-TiO2光催化剂制备及对染 料废水光活性研究 丁鹏赖于民万顺鑫应佶妮宋敏王月 长春师范大学化学学院 利用简单的水热反应法制备丫固体超强酸光催化剂S0427FeA-Ti02o样品经过X- 射线粉末衍射仪（XRD）、扫描电子显微镜（SEM）、红外光谱仪（IR）、失重差 热量热仪（TGA/DSC）等测试手段进行了表征。在可见光照射下测试了该光催化 剂对亚甲基蓝（MB）水溶液的光催化活性，探究了光催化剂用量和初始浓度对 降解效率的影响。结果表明：该光催化剂主要由锐钦矿丁瓜和a-Fe2O3组成，SO,广 主要以螯合双配位方式;结合在FeiA-TiO2表面，S-0强烈的诱导效应使金属与氧 （M-0）键上的电子云强度偏移，导致产生L酸中心，同时也具有B-酸能力，这 些有利于污染物的降解。300°C焙烧的样品具有更高的脱色效率，在亚甲基蓝初 始浓度为6mg/L和催化剂用量为0. 6g/L时，脱色效率达到92. 2%。 SO,27Fe2O3-TiO2光催化剂可以应用于染料废水的净化处理中。 关键词： SO42-/Fe2O3-TiO2;光催化活性;亚甲基蓝;染料废水; 研究方向 为环境污染控制及纳米功能材料。 基金：吉林省人学生创新创业项目（201610205056） Preparation of S042-/Fe203-Ti02 Composite Photocatalyst and Study on their Visible Light Photocatalytic Activity for Dye Wastewater Abstract： SOt2 /Fe2O：-TiO2 photocatalyst were prepared by water thermal method, and its phase structure were characterized by XRD，SEM，IR and TGA/DSC. Using methylene blue as target pollutants, their visible light photocatalytic activity in dye wastewater were studied.八11 results show: the photocatalyst is mainly composed of anatase TiO2 and a -Fe2O3. The high photo-activity of S0i27Fe203-Ti02 can be attributed to S042 being combined with metallic oxide in a chelating bidentate mode. Strong induction effect of S-0 lead to deviating electronic cloud intensity of M-0，which increase the production of Lewis acid center and Bronsted acid. At this time, there arc two types of acid sites (Lewis and Bronsted acid) on the samples, which is benefit for degradation of pollutants and enhancement of transfer of photo-generated carriers. Samples calcinated at 300 °C have higher decolorizing efficiency. Decolorizing efficiency of the 6 mg/L MB solution is 92. 2% by 0. 6 g/L photoeatalyst. The photocatalyst of S0,2/Fe20：-Ti02 can be used in the purification treatment of dye wastewater. Keyword： S042-/Fe203-Ti02; Photocatalytic Activity; Methylene Blue; Dye Wastewater; 水污染的主要来源之一就是来自不同印染工厂的印染染料污水。染料废水中含冇 高含量的有机污染物［1，2］,而且染料废水具有高的显色性和高的碱性位dl。光 催化降解被认为是从污水中去除染料的一种可行的方法1^1。与传统的处理方 法相比，它可以有效并且彻底地毁掉许多生物不可降解污染物的结构稳定性 ［9-12］。然