兔毛白粉成分结构分析及其应用.docVIP

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兔毛白粉成分结构分析及其应用.doc

兔毛白粉成分结构分析及其应用 张毅黎淑婷张昊张转玲 天津工业大学纺织学院 为更好地开发利用兔毛纤维在纺纱过程中产生的兔毛白粉废弃物,釆用扫描电 子显微镜、双缩脲显色法、SDS-聚丙烯酰胺凝胶电泳法、傅里叶红外光谱、X射 线衍射以及差示扫描量热法对从兔毛纤维表面脱落的內粉进行表观结构和成分 结构探宂。结果表明:兔毛白粉是从兔毛表而鳞片脱离下来的物质,长度、宽度 和厚度分别为2050 um、2. 06. 0 um和0. 4°. 7um,兔毛白粉的成分中含有蛋白质, 相对分子质量主要集中在11 ku左右,可被认为是提取角蛋白的良好材料;利用 还原C法从兔毛白粉中进-步提取角蛋白,将其作为一种紫外防护功能添加剂 应用于化妆品屮,在200320 nm的紫外线K测试兔毛白粉,发现兔毛白粉的紫外 线吸收能力优于防晒产品。 关键词: 兔毛白粉;成分结构;角蛋白;紫外吸收; 主要研究方向为特种动物纤维综合利用。 。 基金:农业部财政部国家级专项项目(CARS-44-D-2) Structural characterization and application of rabbit whiting ZHANG Yi LI Shuting ZHANG Hao ZHANG Zhuanling School of Textiles, Tianjin Polytechnic University; Abstract: For a better development and utilization of rabbit whiting produced in the spinning process of rabbit fibers, the rabbit whiting waste was tested by scanning electron microscopy, biuret test, sodium dodecyl sulfate polyacrylamide gel electropheresis, Fourier transform infrared spectroscopy, X-ray diffraction and differential scanning calorimetry to characterize its apparent structure and composition. The experimental results prove that the rabbit whiting is a substance detached from the surface exfoliate of rabbit hair, and has the length, width and thickness of 20-50 u m, 2. 0-6. 0 um and 0. 4-0. 7 um,respectively. And keratin as the main component has a molecular weight of 11 ku approximately- Therefore, rabbit whiting is regarded as a good material for keratin extraction. The keratin was further extracted from rabbit whiting by the sulphitolysis method, which is used as a kind of anti-ultraviolet additive applied in cosmetic. The rabbit whiting has ultraviolet absorption superior to sunscreen products by UV test in the ultraviolet range of 200-320 nm. Keyword: rabbit whiting; component structure; keratin; ultraviolet absorption; 兔毛是一种天然蛋白质纤维,由角蛋白组成,与其他常用的天然动物纤维相比, 兔毛纤维是一种绿色环保、保暖性佳的纺织用保暖材料,具有优异的天然特性 [卜2]。兔毛纤维表而洁白、光滑、洁浄,是重要的纺织工业原料,而且在纺织 加工前不需繁琐清洗,缩短了生产工序的同时也避免洗涤废水对环境的污染, 因此,兔毛作为一种环保纺织原料越来越受到企业的重视和消费者的青睐,但 是兔毛在分梳过程中,其纤维表面会大量地产生一种类似滑石粉物质,人们俗 称白粉,当加工车间相对湿度较高时,內粉易于吸湿而团聚、黏附在机部

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