Synthesis and application in LIB of Ge-材料合成化学课件PPT.pptVIP

Synthesis and application in LIB of Ge Introduction Background Synthesis of Ge nanowires Synthesis of Ge nanoparticles Synthesis of Ge nanocrystalline and films Conclusions Background Ge as anode material for LIB: High capacity – 1600mAh/g in theory forming alloy as Li4.4Ge,that is 4 times of graphite(372mAh/g). Poor cycling capability – because of the large volume expansion (400%) during the alloying process Syntheis of Ge nanowires GeNWs were synthesisized using VLS growth using CVD from GeH4 decomposition onto metalic substrate(stainless steel foil) A high-temperature(520oC) annealing ste