Synthesis of CeO2 Nanorods via Ultrasonication Assisted by Polyethylene Glycol-材料合成化学课件PPT.ppt

* * Synthesis of CeO2 Nanorods via Ultrasonication Assisted by Polyethylene Glycol Main contents Introduction Synthesis dicussion Conclusion Introduction Synthesis Main Materials:PEG600, 0.005 g/mL NaOH, 0.05 g/mL Ce(NO3)3, Deionized water Main Condition:Ultrasonication Process: add gradually (5 mL/min) 0.005 g/mL NaOH solution into the above-mixed solutions, vigorous stirring , ultrasonication, when pH = 10 disperse1 g of PEG600 in 100 mL of 0.05 g/mL Ce(NO3)3 solution;ultrasonication ; room temperature further sonicate for 1 h. rinse repeatedly with alcohol and deionized water, dry at 100 °C in air for 1 day. The end ?chemical equation: Discussion 1) Characteristics of CeO2 Nanorods. XRD ( finger 1) 2) Factors Affecting the Formation of CeO2 Nanorods. A) the surfactant PEG (finger 2) B) ultrasonication without ultrasonication ; (finger 3) the sample without subsequent sonication; the sample sonicated for 10 min; the sample sonicated for 30 min; the sample sonicated for 1 h; (finger 4) the colloidal precipitates aged for days without the subsequent sonication (finger 5) Figure 1 XRD pattern of CeO2 nanorods. Figure 2 TEM image of the agglomerated CeO2 nanoparticles prepared in the absence of PEG. Figure 3 TEM image of the as-synthesized sample without ultrasonic radiation. Figure 4 TEM images of CeO2. (a) The sample without subsequent sonication; (b) the sample sonicated for 10 min; (c) the sample sonicated for 30 min; (d) the sample sonicated for 1 h. Figure 5 SEM image of the as-synthesized product aged for days without subsequent ultrasonication. 3)Possible Formation Mechanism Scheme 1. Possible Formation Mechanism of CeO2 Nanorods Conclusion 1)Polycrystalline CeO2 nanorods have bee